Synthesis, structure and reactivity study of 1,1′-bis(N-ter-butyl-N-hydroxyamino)ferrocene

被引：2

作者：

Carré, F ^{[1
]}

Guérin, C ^{[1
]}

Henner, BJL ^{[1
]}

Uerpmann, C ^{[1
]}

机构：

[1] Univ Montpellier 2, UMR Chim Mol & Org Solide 5637, F-34095 Montpellier 5, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 654卷 / 1-2期

关键词：

ferrocene; radical; hydroxylamine; X-ray;

D O I：

10.1016/S0022-328X(02)01365-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of 1,1'-bis(N-ter-butyl-N-hydroxyamino)ferrocene 1, is described, and the X-ray analysis showed eclipsed positions of the two ter-butylhydroxyamino groups; this structure can be explained by the interactions of the hydroxyl hydrogens with the nitrogen atoms of the other ter-butylhydroxyamino group. This interaction is maintained in solution and may explain that the oxidation of 1 using Ag2O gave a decomposition reaction instead of the expected 1,1'-bis(N-ter-butylaminoxy)ferrocene. (C) 2002 Published by Elsevier Science B.V.

引用

页码：210 / 215

页数：6

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