Synthesis, structure and reactivity study of 1,1′-bis(N-ter-butyl-N-hydroxyamino)ferrocene

被引：2
|
作者：
Carré, F [1 ]
Guérin, C [1 ]
Henner, BJL [1 ]
Uerpmann, C [1 ]
机构：
[1] Univ Montpellier 2, UMR Chim Mol & Org Solide 5637, F-34095 Montpellier 5, France
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 654卷 / 1-2期
关键词：
ferrocene; radical; hydroxylamine; X-ray;
D O I：
10.1016/S0022-328X(02)01365-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of 1,1'-bis(N-ter-butyl-N-hydroxyamino)ferrocene 1, is described, and the X-ray analysis showed eclipsed positions of the two ter-butylhydroxyamino groups; this structure can be explained by the interactions of the hydroxyl hydrogens with the nitrogen atoms of the other ter-butylhydroxyamino group. This interaction is maintained in solution and may explain that the oxidation of 1 using Ag2O gave a decomposition reaction instead of the expected 1,1'-bis(N-ter-butylaminoxy)ferrocene. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码：210 / 215
页数：6
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