Synthesis, structure and reactivity study of 1,1′-bis(N-ter-butyl-N-hydroxyamino)ferrocene

被引：2
|
作者：
Carré, F [1 ]
Guérin, C [1 ]
Henner, BJL [1 ]
Uerpmann, C [1 ]
机构：
[1] Univ Montpellier 2, UMR Chim Mol & Org Solide 5637, F-34095 Montpellier 5, France
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 654卷 / 1-2期
关键词：
ferrocene; radical; hydroxylamine; X-ray;
D O I：
10.1016/S0022-328X(02)01365-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of 1,1'-bis(N-ter-butyl-N-hydroxyamino)ferrocene 1, is described, and the X-ray analysis showed eclipsed positions of the two ter-butylhydroxyamino groups; this structure can be explained by the interactions of the hydroxyl hydrogens with the nitrogen atoms of the other ter-butylhydroxyamino group. This interaction is maintained in solution and may explain that the oxidation of 1 using Ag2O gave a decomposition reaction instead of the expected 1,1'-bis(N-ter-butylaminoxy)ferrocene. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码：210 / 215
页数：6
相关论文
共 50 条
  • [21] SYNTHESIS, STRUCTURE, AND REDOX PROPERTIES OF 1,1′-BIS(ARYLOLIGOTHIENYL)FERROCENES
    Ogawa, Satoshi
    Kobayashi, Haruka
    Muraoka, Hiroki
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2011, 186 (05) : 1238 - 1245
  • [22] Asymmetric synthesis of (S,S)-(+)-1,1'-bis-(methyl-phenyl-phosphino) ferrocene
    Kaloun, EB
    Merdes, R
    Genet, JP
    Uziel, J
    Juge, S
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 529 (1-2) : 455 - 463
  • [23] 1-[N-phenyl(aminomethyl)]silatrane: Synthesis, reactivity and structure
    Lazareva, N. F.
    Sterkhova, I. V.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019, 898
  • [24] Reaction of 1,1"-bis(diazoacetyl)ferrocene with C60 fullerene: synthesis of conformationally rigid fullerene—ferrocene ansa-derivative
    V. I. Sokolov
    T. V. Potolokova
    M. N. Nefedova
    A. S. Peregudov
    Russian Chemical Bulletin, 2003, 52 : 1452 - 1453
  • [25] Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers
    Kovac, Veronika
    Semencic, Mojca Cakic
    Molcanov, Kresimir
    Sabljic, Igor
    Ivekovic, Damir
    Zinic, Mladen
    Rapic, Vladimir
    TETRAHEDRON, 2012, 68 (38) : 7884 - 7891
  • [26] Synthesis and physical properties of ferrocene derivatives (XX):: Crystal structure of a liquid-crystalline ferrocene derivative, 1,1′-bis [9-[4-(4-methoxyphenoxycarbonyl)phenoxy]nonyloxycarbonyl]ferrocene
    Nakamura, Naotake
    Nio, Takahiro
    Okabe, Takashi
    Donnio, Bertrand
    Guillon, Daniel
    Gallani, Jean-Louis
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2007, 466 : 3 - 12
  • [27] 1,1′-Ferrocenylene-Bridged Bis(N-Heterocyclic Olefin) Derivatives
    Guthardt, Robin
    Mellin, Johanna
    Bruhn, Clemens
    Siemeling, Ulrich
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 2022 (02)
  • [28] Synthesis of a series of 1,n′-disubstituted ferrocene derivatives containing disulfides
    Shipman, Patrick O.
    Lafreniere, Matthew A.
    Colquhoun, Craig D. S.
    Kraatz, Heinz-Bernhard
    INORGANICA CHIMICA ACTA, 2012, 391 : 195 - 200
  • [29] Synthesis and intramolecular hydrogen bonding studies of 1-[N-formyl-N',N'-disubstituted thiourea]-1'-[N',N'-disubstituted amide]ferrocene derivatives
    Yuan, YF
    Ye, SM
    Zhang, LY
    Wang, JT
    Wang, HG
    POLYHEDRON, 1997, 16 (13) : 2271 - 2277
  • [30] Reaction of 1,1′-bis(diazoacetyl)ferrocene with C60 fullerene:: synthesis of conformationally rigid fullerene-ferrocene ansa-derivative
    Sokolov, VI
    Potolokova, TV
    Nefedova, MN
    Peregudov, AS
    RUSSIAN CHEMICAL BULLETIN, 2003, 52 (06) : 1452 - 1453
12345