Pulsed plasma polymerization of perfluorocyclohexane

被引：60
作者：
Hynes, AM [1 ]
Shenton, MJ [1 ]
Badyal, JPS [1 ]
机构：
[1] UNIV DURHAM, DEPT CHEM, SCI LABS, DURHAM DH1 3LE, ENGLAND
来源：
MACROMOLECULES | 1996年 / 29卷 / 12期
关键词：
D O I：
10.1021/ma951747q
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Pulsed versus continuous wave plasma polymerization of perfluorocyclohexane is compared as a function of duty cycle off-time, on-time, and peak power. The chemical composition of the deposited films has been determined by X-ray photoelectron spectroscopy (XPS). A greater retention of the chemical structure associated with the precursor molecule is found for the pulsed plasma polymerization experiments. This can be rationalized in terms of the relative perturbation of reactive species contained in the electrical discharge.
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页码：4220 / 4225
页数：6
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