Pulsed plasma polymerization of perfluorocyclohexane

被引：60

作者：

Hynes, AM ^{[1
]}

Shenton, MJ ^{[1
]}

Badyal, JPS ^{[1
]}

机构：

[1] UNIV DURHAM, DEPT CHEM, SCI LABS, DURHAM DH1 3LE, ENGLAND

来源：

MACROMOLECULES | 1996年 / 29卷 / 12期

关键词：

D O I：

10.1021/ma951747q

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Pulsed versus continuous wave plasma polymerization of perfluorocyclohexane is compared as a function of duty cycle off-time, on-time, and peak power. The chemical composition of the deposited films has been determined by X-ray photoelectron spectroscopy (XPS). A greater retention of the chemical structure associated with the precursor molecule is found for the pulsed plasma polymerization experiments. This can be rationalized in terms of the relative perturbation of reactive species contained in the electrical discharge.

引用

页码：4220 / 4225

页数：6

共 39 条

[1]

BELL AT, 1980, TOP CURR CHEM, V94, P43

[2]

BIEDERMAN H, 1990, ADV POLYM SCI, V95, P57

[3] EXCITED-STATES OF CF-4 PLASMA FOR POLYMERIZATION OF TMPTA MONOMER [J].

BRETAGNE, J ;

EPAILLARD, F ;

RICARD, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (02) :323-328

[4]

Budzikiewicz H, 1967, MASS SPECTROMETRY OR

[5]

Chambers R.D., 1973, Fluorine in Organic Chemistry

[6]

Christie A.B., 1989, Methods of surface analysis

[7] ESCA APPLIED TO POLYMERS .27. PLASMA POLYMERIZATION .2. ESCA INVESTIGATION OF POLYMERS SYNTHESIZED BY EXCITATION OF INDUCTIVELY COUPLED RF PLASMA IN PERFLUOROBENZENE AND PERFLUOROCYCLOHEXANE [J].

CLARK, DT ;

SHUTTLEWORTH, D .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (01) :27-46

[8]

CLARK DT, 1978, POLYM SURFACES

[9]

CLAROTTI G, 1991, MAKROMOL CHEM, V192, P2581

[10] PLASMA DEPOSITION OF THIN FLUOROCARBON FILMS FOR INCREASED MEMBRANE HEMOCOMPATIBILITY [J].

CLAROTTI, G ;

SCHUE, F ;

SLEDZ, J ;

GECKELER, KE ;

GOPEL, W ;

ORSETTI, A .

JOURNAL OF MEMBRANE SCIENCE, 1991, 61 :289-301

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