Preparation of two novel C-60 and C-70 fullerene pyrrolidine derivatives

被引:10
作者
Zheng, DG [1 ]
Li, YL [1 ]
Yang, JK [1 ]
Zhu, DB [1 ]
机构
[1] SHANGRAO TEACHERS COLL,SHANGRAO 334001,JIANGXI,PEOPLES R CHINA
来源
FULLERENE SCIENCE AND TECHNOLOGY | 1996年 / 4卷 / 05期
基金
中国国家自然科学基金;
关键词
D O I
10.1080/10641229608001163
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
C-60 reacted with paraformaldehyde and DL-valine in dry toluene under nitrogen to give a monoadduct. Under the similar conditions,C-70 gave a bisadduct. Both products were characterized by FT-IR,UV-Vis,EI-MS and NMR. The studies of the cyclic voltammetry showed that the abilities of donating electron of the products were increased compared to C-60 and C-70,respectively.
引用
收藏
页码:1067 / 1072
页数:6
相关论文
共 8 条
[1]  
Han HX, 1995, CHINESE CHEM LETT, V6, P201
[2]  
HIRSCH A, 1993, ANGEW CHEM INT EDIT, V32, P1138, DOI 10.1002/anie.199311381
[3]   IMPROVED PURIFICATION OF C-60 AND FORMATION OF SIGMA-HOMOAROMATIC AND PI-HOMOAROMATIC METHANO-BRIDGED FULLERENES BY REACTION WITH ALKYL DIAZOACETATES [J].
ISAACS, L ;
WEHRSIG, A ;
DIEDERICH, F .
HELVETICA CHIMICA ACTA, 1993, 76 (03) :1231-1250
[4]   SOLID C-60 - A NEW FORM OF CARBON [J].
KRATSCHMER, W ;
LAMB, LD ;
FOSTIROPOULOS, K ;
HUFFMAN, DR .
NATURE, 1990, 347 (6291) :354-358
[5]   THE INFRARED AND ULTRAVIOLET-ABSORPTION SPECTRA OF LABORATORY-PRODUCED CARBON DUST - EVIDENCE FOR THE PRESENCE OF THE C-60 MOLECULE [J].
KRATSCHMER, W ;
FOSTIROPOULOS, K ;
HUFFMAN, DR .
CHEMICAL PHYSICS LETTERS, 1990, 170 (2-3) :167-170
[6]  
MCLAFFERTY FW, 1992, ACCOUNTS CHEM RES, V25, P157
[7]   THE CHEMISTRY OF FULLERENES [J].
TAYLOR, R ;
WALTON, DRM .
NATURE, 1993, 363 (6431) :685-693
[8]   GLYCOSYLIDENE CARBENES .9. FULLERENE SUGARS - PREPARATION OF ENANTIOMERICALLY PURE, SPIRO-LINKED C-GLYCOSIDES OF C-60 [J].
VASELLA, A ;
UHLMANN, P ;
WALDRAFF, CAA ;
DIEDERICH, F ;
THILGEN, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (10) :1388-1390