Crystal structure of the bis[zinc(II)-hydroxide-(μ-perchlorate)-triaqua] complex

被引：2
|
作者：
Li, YH [1 ]
Ye, Q [1 ]
Tang, YZ [1 ]
Xiong, RG [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 11期
关键词：
crystal structure; zinc; hydrogen bonding; perchlorate;
D O I：
10.1002/zaac.200400201
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Colorless single crystals of the title compound were accidentally obtained by a reaction of p-sulfophenyl ala nine with zinc perchlorate. The crystal structure (monoclinic, P2(1)/c, Z = 4, a = 5.9031(7), b = 13.5404(16), c = 9.7932(8) Angstrom, beta = 126.438(5)degrees, V = 629.74(12) Angstrom(3), R-1[I>2sigma(I)] = 0.0276, wR(2)(all) = 0.0844) reveals a discrete dinuclear [Zn(OH)(mu-ClO4)(HO)(3)](2) in which each perchlorate anion acts as a bidentate bridging linker to bind two Zn atoms whereas the hydroxy group is a terminal group. Thus, the local surrounding around the zinc atom can be best described as a slightly distorted octahedron.
引用
收藏
页码：1553 / 1554
页数：2
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