Chemo-Enzymatic Synthesis and Characterization of Renewable Thermoplastic and Thermoset Isocyanate-Free Poly(hydroxy)urethanes from Ferulic Acid Derivatives

被引：57
作者：
Menard, Raphael [1 ,2 ]
Caillol, Sylvain [2 ]
Allais, Florent [1 ,3 ]
机构：
[1] CEBB, AgroParisTech, ABI, Chaire Agrobiotechnol Ind, 3 Rue Rouges Terres, F-51110 Pomacle, France
[2] ENSCM, UM, CNRS, Inst Charles Gerhardt,UMR 5253, 8 Rue Ecole Normale, F-34296 Montpellier, France
[3] Univ Paris Saclay, CNRS, INRA, AgroParisTech,UMR GMPA 782, Ave Lucien Bretignieres, F-78850 Thiverval Grignon, France
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 02期
关键词：
Chemo-enzymatic synthesis; Nonfeed product valorization; CO2; sequestration; Ferulic acid; Fully biobased NIPU; Thermosets and thermoplastics; Tunable material properties; 5-MEMBERED CYCLIC CARBONATE; THERMAL-PROPERTIES; MODEL REACTION; EPOXY-RESINS; CO2; FIXATION; POLYURETHANES; POLYHYDROXYURETHANES; POLYADDITION; POLYMERS; AMINES;
D O I：
10.1021/acssuschemeng.6b02022
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study presents the syntheses and characterization of renewable nonisocyanate polyurethanes (NIPUs) from a new family of aromatic C-5-cyclocarbonate precursors with different functionalities obtained from nontoxic ferulic acid derivatives by glycidylation and carbonation under high carbon dioxide pressure. Depending on the functionality, linear NIPU chains (thermoplastics) or cross-linked NIPU networks (thermosets) have been obtained. The thermoplastic NIPUs molar masses were determined using SEC and H-1 NMR. The thermal and thermo-mechanical properties of the NIPUs were assessed by DSC, DMA (for thermosets), and TGA to determine the influence of the NIPU chemical structure on its properties. The range of T-g obtained (17-72 degrees C) was efficiently correlated with the degree of freedom and the molar mass of the NIPU repeat unit.
引用
收藏
页码：1446 / 1456
页数：11
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