Phase transitions, structure and ion conductivity of zirconium hydrogen phosphates, H1±XZr2-XMX(PO4)3•H2O (M = Nb, Y)

被引：15

作者：

Stenina, I. A. ^{[1
]}

Zhizhin, M. G. ^{[2
]}

Lazoryak, B. I. ^{[2
]}

Yaroslavtsev, A. B. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Moscow 119992, Russia

来源：

MATERIALS RESEARCH BULLETIN | 2009年 / 44卷 / 07期

关键词：

Inorganic compounds; Phase transactions; Ionic conductivity; Thermal expansion; THERMAL-EXPANSION; CRYSTAL-STRUCTURES;

D O I：

10.1016/j.materresbull.2009.01.011

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Structure transformations and proton conductivity of hydrogen zirconium phosphates with the NASICON structure, H1 +/- XZr2-XMX(PO4)(3)center dot H2O (X = 0, 0.02, and 0.1, M = Nb, Y), were studied by X-ray powder diffraction, calorimetry, IR- and impedance spectroscopy. Substitution of zirconium by niobium leads to decrease of the lattice parameters, while yttrium doping leads to their increase. H0.9Zr1.9Nb0.1(PO4)(3) structure was determined at 493 and 733 K. This phase crystallizes in rhombohedral space group R (3) over barc with lattice parameters a = 8.8564(5) angstrom, c = 22.700(1) angstrom at 493 K and a = 8.8470(2) angstrom, c = 22.7141(9) angstrom at 733 K. The a parameter and lattice volume were found to decrease with temperature increasing. Structure transformations upon heating are caused mainly by the decrease of the M1 site and C cavities. Ion conductivity of obtained materials was found to increase in humid atmosphere. Activation energies of conductivity were calculated. Rhombohedral-triclinic phase transition found by X-ray powder diffraction was proved by calorimetry data. According to XRD and IR spectroscopy data hydrogen bond in HZr2(PO4)(3) was found to be weaker than in hydrated material. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1608 / 1612

页数：5

共 50 条

[41] Reactions of hexanuclear niobium and tantalum halide clusters with mercury(II) halides .1. Synthesis and structures of the semiconducting compounds [M6Br12(H2O)(6)][HgBr4]center dot 12H(2)O, M=Nb, Ta
Vojnovic, M
Antolic, S
KojicProdic, B
Brnicevic, N
Miljak, M
Aviani, I
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (08): : 1247 - 1254
[42] Transition metal salts of quinoline: synthesis, structure and magnetic behavior of (QuinH)2[MX4]•2H2O [Quin = quinoline; M = Mn, Co, Cu, Zn], (QuinH)2[MnBr2(H2O)2](Br)2 and (QuinH)[Cu(Quin)Br3]
Landee, Christopher P.
Monroe, Jeffrey C.
Kotarba, Robert
Polson, Matthew
Wikaira, Jan L.
Turnbull, Mark M.
JOURNAL OF COORDINATION CHEMISTRY, 2018, 71 (20) : 3342 - 3363
[43] Extended network via hydrogen bond linkages of coordination compounds:: synthesis, crystal structure and thermal behaviour of the complexes [M(L)2(NO3)2] (MII = Cu, Co) and [Ni(L)2(H2O)2][(NO3)2] (L = malonamide)
Rodríguez-Martín, Y
Luis, PAL
Ruiz-Pérez, C
INORGANICA CHIMICA ACTA, 2002, 328 (01) : 169 - 178
[44] Complex hydroxides of chromium:: Na9[Cr(ON)6]2(OH)3•6H2O and Na4[Cr(OH)6]X•H2O (X = Cl, (S2)1/2) -: Synthesis, crystal structure, and thermal behaviour
Hinz, D
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (04): : 1004 - 1011
[45] A new 1-D polymeric chains of (C2H5N4)[CdCl3(H2O)] perovskite: elaboration, structure, surface interaction analysis, vibrational study, and thermal behavior
Mrad, Mohamed Habib
CHEMICAL PAPERS, 2023, 77 (10) : 6397 - 6407
[46] SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURE OF [PD(DPPP)(H2O)(TSO)] [TSO] (DPPP=1,3-BIS(DIPHENYLPHOSPHINO)PROPANE - TSO=P-CH3C6H4SO3), A CATALYTIC SPECIES IN CO-C2H4 COPOLYMERIZATION
BENETOLLO, F
BERTANI, R
BOMBIERI, G
TONIOLO, L
INORGANICA CHIMICA ACTA, 1995, 233 (1-2) : 5 - 9
[47] Uptake of ethylene by sulfur-bridged cubane-type molybdenum/tungsten-nickel clusters [M(3)NiS(4)(H2O)(10)](4+) (M(3)=Mo-3, Mo2W, MoW2, W-3): Syntheses, structures and H-1 NMR spectra
Shibahara, T
Sakane, G
Maeyama, M
Kobashi, H
Yamamoto, T
Watase, T
INORGANICA CHIMICA ACTA, 1996, 251 (1-2) : 207 - 225
[48] Hydrogen bonding and π-π interactions in the cocrystal salt [Fe(bpe)2(H2O)4](TCEP)2•2(bpe) [bpe is trans-1,2-bis(pyridin-4-yl)ethene and TCEP is 1,1,3,3-tetracyano-2-ethoxypropenide]
Addala, Abderrezak
Geiger, David K.
Setifi, Zouaoui
Setifi, Fatima
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2019, 75 : 348 - +
[49] The effect of the perturbation of hydrogen bonding on the Zn(II) coordination geometry:: synthesis and structure of [Zn(BIP) (H2O)2] (ClO4)2 (BIP=1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propane)
Long, LS
Chen, XM
Ji, LN
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (05) : 181 - 183
[50] NQR, DSC, and X-Ray Structure Studies of Pyridinium Tetrabromozincate and Pyridinium Tetrabromocadmate (C5H5NH)2MBr4 • nH2O (M = Zn and Cd; n=0, 1); Phase Transitions and Weak Hydrogen Bond Interactions
Ishihara, Hideta
Hatano, Naoko
Horiuchi, Keizo
Terao, Hiromitsu
Svoboda, Ingrid
Fuess, Hartmut
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2011, 66 (12): : 1261 - 1269

← 1 2 3 4 5 →