Nanostructured MnO2:: Hydrothermal synthesis and electrochemical properties as a supercapacitor electrode material

被引:355
作者
Subramanian, V.
Zhu, Hongwei
Wei, Bingqing [1 ]
机构
[1] Louisiana State Univ, Dept Elect & Comp Engn, Baton Rouge, LA 70803 USA
[2] Louisiana State Univ, Ctr Computat & Technol, Baton Rouge, LA 70803 USA
基金
美国国家科学基金会;
关键词
MnO2; nanorods; hydrothermal; supercapacitor; redox; aqueous electrolyte;
D O I
10.1016/j.jpowsour.2006.04.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structural, morphological and electrochemical properties of the hydrothermally prepared manganese oxide (MnO2) nanostructures are discussed in this paper. tnteresting nanostructures of MnO2, mixture of nanostructured surface with a distinct plate-like morphology and nanorods, have been prepared by employing hydrothermal synthesis under mild conditions. The specific surface area of the prepared material was 132 m(2) g(-1). Electrochemical properties of the synthesized nanostructured material were studied using galvanostatic cycling and cyclic voltammetry in a mild aqueous electrolyte that showed a high specific capacitance of 168 Fg(-1). In addition, the synthesized nanomaterial showed a good reversibility and cycling stability. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:361 / 364
页数:4
相关论文
共 14 条
[1]  
Conway B. E., 1999, ELECTROCHEMICAL CAPA
[2]   The role and utilization of pseudocapacitance for energy storage by supercapacitors [J].
Conway, BE ;
Birss, V ;
Wojtowicz, J .
JOURNAL OF POWER SOURCES, 1997, 66 (1-2) :1-14
[3]   Transmission electron microscopy and electron energy-loss spectroscopy analysis of manganese oxide nanowires [J].
Du, GH ;
Yuan, ZY ;
Van Tendeloo, G .
APPLIED PHYSICS LETTERS, 2005, 86 (06) :1-3
[4]   Synthesis and characterization of MnO2-based mixed oxides as supercapacitors [J].
Kim, H ;
Popov, BN .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (03) :D56-D62
[5]   Supercapacitor behavior with KCl electrolyte [J].
Lee, HY ;
Goodenough, JB .
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 144 (01) :220-223
[6]   Characterization of sol-gel-derived cobalt oxide xerogels as electrochemical capacitors [J].
Lin, C ;
Ritter, JA ;
Popov, BN .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (12) :4097-4103
[7]   Porous nickel oxide/nickel films for electrochemical capacitors [J].
Liu, KC ;
Anderson, MA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :124-130
[8]   Novel electrode materials for thin-film ultracapacitors: Comparison of electrochemical properties of sol-gel-derived and electrodeposited manganese dioxide [J].
Pang, SC ;
Anderson, MA ;
Chapman, TW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (02) :444-450
[9]   Hydrothermal synthesis and pseudocapacitance properties of MnO2 nanostructures [J].
Subramanian, V ;
Zhu, HW ;
Vajtai, R ;
Ajayan, PM ;
Wei, BQ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (43) :20207-20214
[10]   Influence of microstucture on the charge storage properties of chemically synthesized manganese dioxide [J].
Toupin, M ;
Brousse, T ;
Bélanger, D .
CHEMISTRY OF MATERIALS, 2002, 14 (09) :3946-3952