Effect of temperature on internal potential barriers in polymer-derived amorphous ceramics

被引:2
作者
Li, Hao [1 ]
Ma, Baisheng [2 ]
An, Linan [1 ]
机构
[1] Univ Cent Florida, Dept Mat Sci & Engn, Orlando, FL 32816 USA
[2] Dongguan Univ Technol, Sch Mech Engn, Dongguan 523808, Guangdong, Peoples R China
关键词
Polymer-derived ceramics; Internal barrier; Schottky barrier; IMPEDANCE SPECTROSCOPY; GIANT PIEZORESISTIVITY; BEHAVIOR; CARBONITRIDE; OXIDATION;
D O I
10.1016/j.ceramint.2019.03.228
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The behavior of the internal potential barrier in a polymer-derived amorphous ceramic was studied by measuring its complex impedance spectra at various dc bias and temperatures. The results showed that the bias-dependent interfacial capacitance can be described by the double Schottky barrier model. Increasing temperature caused the increase in the charge-carrier concentration and decrease in the barrier height, following Arrhenius dependence. The phenomena are correlated to the electronic structure of the free-carbon phase and the amorphous matrix phase in the material.
引用
收藏
页码:13575 / 13578
页数:4
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