Trimetallic Zeolitic imidazolite framework-derived Co nanoparticles@CoFe-nitrogen-doped porous carbon as bifunctional electrocatalysts for Zn-air battery

被引：37
作者：
Hao, Rui [1 ,2 ]
Chen, Jingjing [2 ]
Wang, Zhenyu [2 ]
Huang, Yanping [1 ]
Liu, Penggao [1 ]
Yan, Jun [1 ]
Liu, Kaiyu [1 ]
Liu, Chen [3 ]
Lu, Zhouguang [2 ]
机构：
[1] Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Chem Power Sources, Changsha 410083, Peoples R China
[2] Southern Univ Sci & Technol, Guangdong Prov Key Lab Energy Mat Elect Power, Shenzhen Key Lab Hydrogen Energy, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
[3] Shenzhen Univ, Coll Mat Sci & Engn, Guangdong Res Ctr Interfacial Engn Funct Mat, Shenzhen 518060, Peoples R China
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2021年 / 586卷
基金：
中国国家自然科学基金;
关键词：
Oxygen reduction reaction; Oxygen evolution reaction; Metal-organic framework; Zn-air battery; EFFICIENT OXYGEN REDUCTION; ORGANIC FRAMEWORKS; GRAPHENE; IDENTIFICATION; NANOSHEETS; SITES; ALLOY; IRON;
D O I：
10.1016/j.jcis.2020.10.130
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Searching for high active, low cost and durable catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) remains challenge in developing metal-air battery cathodes. Herein, we proposed a novel bifunctional catalyst derived from the pyrolysis of Co/Fe/Zn trimetallic zeolitic imidazolite framework. The obtained Co@CoFe0.01-N-C catalyst displays desirable activity for both ORR and OER (E-1/2 = 0.844 V, E-j=10 = 1.654 V). The Zn-air battery equipped with Co@CoFe0.01-N-C catalyst on the cathode exhibits a high peak power density of 174.1 mW cm(2), which is much superior than that of commercial 20% Pt/C (87.6 mW cm(2)). Significantly, the designed Co@CoFe0.01-N-C presents an outstanding stability for over 100 h in rechargeable Zn-air battery. (C) 2020 Elsevier Inc. All rights reserved.
引用
收藏
页码：621 / 629
页数：9
相关论文
共 39 条
[1]   From 3D ZIF Nanocrystals to Co-Nx/C Nanorod Array Electrocatalysts for ORR, OER, and Zn-Air Batteries [J].
Amiinu, Ibrahim Saana ;
Liu, Xiaobo ;
Pu, Zonghua ;
Li, Wenqiang ;
Li, Qidong ;
Zhang, Jie ;
Tang, Haolin ;
Zhang, Haining ;
Mu, Shichun .
ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (05)
[2]   A novel Mn/Co dual nanoparticle decorated hierarchical carbon structure derived from a biopolymer hydrogel as a highly efficient electro-catalyst for the oxygen reduction reaction [J].
Cao, Lujie ;
Wang, Zhenyu ;
Liu, Jinlong ;
Wang, Bingxue ;
Wang, Zhiqiang ;
Yang, Mingyang ;
Pan, Hui ;
Lu, Zhouguang .
CHEMICAL COMMUNICATIONS, 2019, 55 (92) :13900-13903
[3]   Synergistic Effects of C/α-MoC and Ag for Efficient Oxygen Reduction Reaction [J].
Cao, Lujie ;
Tao, Pengpeng ;
Li, Minchan ;
Lyu, Fucong ;
Wang, Zhenyu ;
Wu, Sisi ;
Wang, Wenxi ;
Huo, Yifeng ;
Huang, Li ;
Lu, Zhouguang .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (04) :779-784
[4]   Co-Ni Alloy Encapsulated by N-doped Graphene as a Cathode Catalyst for Rechargeable Hybrid Li-Air Batteries [J].
Chang, Zheng ;
Yu, Feng ;
Liu, Zaichun ;
Peng, Shou ;
Guan, Min ;
Shen, Xiaoxiao ;
Zhao, Shulin ;
Liu, Nian ;
Wu, Yuping ;
Chen, Yuhui .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (04) :4366-4372
[5]   Co nanoparticle embedded in atomically-dispersed Co-N-C nanofibers for oxygen reduction with high activity and remarkable durability [J].
Cheng, Qingqing ;
Han, Shaobo ;
Mao, Kun ;
Chen, Chi ;
Yang, Lijun ;
Zou, Zhiqing ;
Gu, Meng ;
Hu, Zheng ;
Yang, Hui .
NANO ENERGY, 2018, 52 :485-493
[6]   Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst [J].
Chung, Hoon T. ;
Cullen, David A. ;
Higgins, Drew ;
Sneed, Brian T. ;
Holby, Edward F. ;
More, Karren L. ;
Zelenay, Piotr .
SCIENCE, 2017, 357 (6350) :479-483
[7]   Well-Defined ZIF-Derived Fe-N Codoped Carbon Nanoframes as Efficient Oxygen Reduction Catalysts [J].
Deng, Yijie ;
Dong, Yuanyuan ;
Wang, Guanghua ;
Sun, Kailing ;
Shi, Xiudong ;
Zheng, Long ;
Li, Xiuhua ;
Liao, Shijun .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (11) :9699-9709
[8]   Boron- and Nitrogen-Doped Graphene Quantum Dots/Graphene Hybrid Nanoplatelets as Efficient Electrocatalysts for Oxygen Reduction [J].
Fei, Huilong ;
Ye, Ruquan ;
Ye, Gonglan ;
Gong, Yongji ;
Peng, Zhiwei ;
Fan, Xiujun ;
Samuel, Errol L. G. ;
Ajayan, Pulickel M. ;
Tour, James M. .
ACS NANO, 2014, 8 (10) :10837-10843
[9]   Hierarchically mesoporous nickel-iron nitride as a cost-efficient and highly durable electrocatalyst for Zn-air battery [J].
Fu, Gengtao ;
Cui, Zhiming ;
Chen, Yifan ;
Xu, Lin ;
Tang, Yawen ;
Goodenough, John B. .
NANO ENERGY, 2017, 39 :77-85
[10]   A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries [J].
Han, Man Huon ;
Gonzalo, Elena ;
Singh, Gurpreet ;
Rojo, Teofilo .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (01) :81-102
1234