Role of solvents on the oxygen reduction and evolution of rechargeable Li-O2battery

被引：36

作者：

Christy, Maria ^{[1
]}

Arul, Anupriya ^{[2
]}

Zahoor, Awan ^{[4
]}

Moon, Kwang Uk ^{[3
]}

Oh, Mi Young ^{[1
]}

Stephan, A. Manuel ^{[5
]}

Nahm, Kee Suk ^{[1
,2
,3
]}

机构：

[1] Chonbuk Natl Univ, R&D Educ Ctr Fuel Cell Mat Syst, Jeonju 561756, South Korea

[2] Chonbuk Natl Univ, Dept Energy Storage Convers Engn, Jeonju 561756, South Korea

[3] Chonbuk Natl Univ, Sch Chem Engn, Jeonju 561756, South Korea

[4] NED Univ Engn & Technol, Dept Chem Engn, Karachi 75270, Pakistan

[5] Cent Elect Res Inst, Elect Power Syst Div, Karaikkudi 630006, Tamil Nadu, India

来源：

JOURNAL OF POWER SOURCES | 2017年 / 342卷

关键词：

Lithium-oxygen battery; Electrolytes; Solvents; Electrocatalytic activity; Overpotential; LI-AIR BATTERIES; DIMETHYL-SULFOXIDE; LI-O-2; BATTERIES; LITHIUM; ELECTROLYTE; METAL; REVERSIBILITY; PERFORMANCE; LIMITATIONS; STABILITY;

D O I：

10.1016/j.jpowsour.2016.12.119

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The choice of electrolyte solvent is expected to play a key role in influencing the lithium-oxygen battery performance. The electrochemical performances of three electrolytes composed of lithium bis (trifluoromethane sulfonyl) imide (LiTFSI) salt and different solvents namely, ethylene carbonate/propylene carbonate (EC/PC), tetra ethylene glycol dimethyl ether (TEGDME) and dimethyl sulfoxide (DMSO) are investigated by assembling lithium oxygen cells. The electrolyte composition significantly varied the specific capacity of the battery. The choice of electrolyte also influences the overpotential, cycle life, and rechargeability of the battery. Electrochemical impedance spectra, cyclic voltammetry, and chronoamperometry were utilized to determine the reversible reactions associated with the air cathode. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：825 / 835

页数：11

共 51 条

[1] A polymer electrolyte-based rechargeable lithium/oxygen battery [J].

Abraham, KM ;

Jiang, Z .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :1-5

[2] Current density dependence of peroxide formation in the Li-O2 battery and its effect on charge [J].

Adams, Brian D. ;

Radtke, Claudio ;

Black, Robert ;

Trudeau, Michel L. ;

Zaghib, Karim ;

Nazar, Linda F. .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1772-1778

[3] Evaluation and electrochemical analyses of cathodes for lithium-air batteries [J].

Adams, James ;

Karulkar, Mohan ;

Anandan, Venkataramani .

JOURNAL OF POWER SOURCES, 2013, 239 :132-143

[4] THE ELECTROCHEMISTRY OF NOBLE-METAL ELECTRODES IN APROTIC ORGANIC-SOLVENTS CONTAINING LITHIUM-SALTS [J].

AURBACH, D ;

DAROUX, M ;

FAGUY, P ;

YEAGER, E .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 297 (01) :225-244

[5] A critical review on lithium-air battery electrolytes [J].

Balaish, Moran ;

Kraytsberg, Alexander ;

Ein-Eli, Yair .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (07) :2801-2822

[6] In situ investigation of pore clogging during discharge of a Li/O2 battery by electrochemical impedance spectroscopy [J].

Bardenhagen, Ingo ;

Yezerska, Olga ;

Augustin, Matthias ;

Fenske, Daniela ;

Wittstock, Arne ;

Baeumer, Marcus .

JOURNAL OF POWER SOURCES, 2015, 278 :255-264

[7] Predicting Solvent Stability in Aprotic Electrolyte Li-Air Batteries: Nucleophilic Substitution by the Superoxide Anion Radical (O2•-) [J].

Bryantsev, Vyacheslav S. ;

Giordani, Vincent ;

Walker, Wesley ;

Blanco, Mario ;

Zecevic, Strahinja ;

Sasaki, Kenji ;

Uddin, Jasim ;

Addison, Dan ;

Chase, Gregory V. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (44) :12399-12409

[8] A rotating ring disk electrode study of the oxygen reduction reaction in lithium containing non aqueous electrolyte [J].

Calvo, E. J. ;

Mozhzhukhina, N. .

ELECTROCHEMISTRY COMMUNICATIONS, 2013, 31 :56-58

[9] Highly Active and Durable Core-Corona Structured Bifunctional Catalyst for Rechargeable Metal-Air Battery Application [J].

Chen, Zhu ;

Yu, Aiping ;

Higgins, Drew ;

Li, Hui ;

Wang, Haijiang ;

Chen, Zhongwei .

NANO LETTERS, 2012, 12 (04) :1946-1952

[10] A Critical Review of Li/Air Batteries [J].

Christensen, Jake ;

Albertus, Paul ;

Sanchez-Carrera, Roel S. ;

Lohmann, Timm ;

Kozinsky, Boris ;

Liedtke, Ralf ;

Ahmed, Jasim ;

Kojic, Aleksandar .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (02) :R1-R30

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