Controllable Growth of Nanocrystalline Diamond Films by Hot-Filament Chemical Vapor Deposition Method

被引:5
作者
Li, Yunlong [1 ]
Li, Junjie [1 ]
Wang, Qiang [1 ]
Yang, Yang [1 ]
Gu, Changzhi [1 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China
关键词
Nanocrystalline Diamond Films; CH4; Concentration; Bias Current; ION-BOMBARDMENT; FIELD-EMISSION; NUCLEATION; SUBSTRATE; HYDROGEN; BIAS; CVD;
D O I
10.1166/jnn.2009.C088
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanocrystalline diamond (NCD) films are deposited on Si wafer by using bias-assisted hot-filament chemical vapor deposition (HFCVD) method. The average grain size was controllable by varying CH, concentration. The scanning electron microscopy (SEM), Raman scattering spectroscopy and X-ray diffraction (XRD) were used to investigate the morphology, phase purity, and crystallinity of NCD films, respectively. Furthermore, we found that the morphological evolving of NCD films was corresponding to the variation of bias current, which might have close relation to thermal field electrons emission from NCD films at high temperature during the growth process, and then the related mechanism was discussed.
引用
收藏
页码:1062 / 1065
页数:4
相关论文
共 18 条
[11]   The effect of ion bombardment on the nucleation of CVD diamond [J].
Sun, XS ;
Wang, N ;
Woo, HK ;
Zhang, WJ ;
Yu, G ;
Bello, I ;
Lee, CS ;
Lee, ST .
DIAMOND AND RELATED MATERIALS, 1999, 8 (8-9) :1414-1417
[12]   The relationship between the spatially resolved field emission characteristics and the Raman spectra of a nanocrystalline diamond cold cathode [J].
Talin, AA ;
Pan, LS ;
McCarty, KF ;
Felter, TE ;
Doerr, HJ ;
Bunshah, RF .
APPLIED PHYSICS LETTERS, 1996, 69 (25) :3842-3844
[13]   RAMAN SPECTRUM OF GRAPHITE [J].
TUINSTRA, F ;
KOENIG, JL .
JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (03) :1126-&
[14]   Experimental and theoretical studies of diamond nucleation on silicon by biased hot filament chemical vapor deposition [J].
Wang, BB ;
Wang, WL ;
Liao, KJ ;
Xiao, JL .
PHYSICAL REVIEW B, 2001, 63 (08)
[15]   Diamond cone arrays with controlled morphologies formed by self-organized selective ions sputtering [J].
Wang, Q. ;
Gu, C. Z. ;
Xu, Z. ;
Li, J. J. ;
Wang, Z. L. ;
Bai, X. D. ;
Cui, Z. .
JOURNAL OF APPLIED PHYSICS, 2006, 100 (03)
[16]  
Wang WL, 1997, ACTA PHYS SIN-OV ED, V6, P517
[17]   Combined effects of argon addition and substrate bias on the formation of nanocrystalline diamond films by chemical vapor deposition [J].
Yang, TS ;
Lai, JY ;
Wong, MS ;
Cheng, CL .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (09) :4912-4917
[18]   Synthesis and electron field emission of nanocrystalline diamond thin films grown from N-2/CH4 microwave plasmas [J].
Zhou, D ;
Krauss, AR ;
Qin, LC ;
McCauley, TG ;
Gruen, DM ;
Corrigan, TD ;
Chang, RPH ;
Gnaser, H .
JOURNAL OF APPLIED PHYSICS, 1997, 82 (09) :4546-4550