Palladium-Catalyzed Aminosulfonylation of Aryl Iodides by using Na2SO3 as the SO2 Source

被引：78
作者：
Li, Wanfang [1 ]
Li, Haoquan [1 ]
Langer, Peter [1 ]
Beller, Matthias [1 ]
Wu, Xiao-Feng [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 15期
关键词：
Synthetic methods; Cross-coupling; Aminosulfonylation; Palladium; Sulfur; SULFUR-DIOXIDE INSERTION; EX-SITU; HALIDES; 3-COMPONENT; CARBONYLATION; ACCESS; SULFONAMIDE; DABSO; ACIDS; SCOPE;
D O I：
10.1002/ejoc.201402212
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We realized an interesting palladium-catalyzed aminosulfonylation of aryl iodides by using Na2SO3 as a cheap SO2 source. In most cases, the yields were comparable to those reported by using the 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABCO2SO(2), DABSO) as the SO2 source.
引用
收藏
页码：3101 / 3103
页数：3
相关论文
共 41 条
  • [1] SULFONE FORMATION DURING SULFINATION OF THE ALKYL GRIGNARD REAGENT
    ALLEN, P
    REHL, WR
    FUCHS, PE
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1955, 20 (09) : 1237 - 1239
  • [2] [Anonymous], 2013, ANGEW CHEM, V125, P12911
  • [3] [Anonymous], 2014, ANGEW CHEM, V126, P2483
  • [4] [Anonymous], 2013, ANGEW CHEM, V125, P9945
  • [5] Synthetic Routes of Sulfonamide Derivatives: A Brief Review
    Ashfaq, Muhammad
    Shah, Syed Shoaib Ahmad
    Najjam, Tayyaba
    Shaheen, Salma
    Rivera, Gildardo
    [J]. MINI-REVIEWS IN ORGANIC CHEMISTRY, 2013, 10 (02) : 160 - 170
  • [6] Beller M., 2013, TRANSITION METAL CAT
  • [7] Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology
    Bisseret, Philippe
    Blanchard, Nicolas
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, 11 (33) : 5393 - 5398
  • [8] Palladium-Catalyzed N-Acylation of Monosubstituted Ureas Using Near-Stoichiometric Carbon Monoxide
    Bjerglund, Klaus
    Lindhardt, Anders T.
    Skrydstrup, Troels
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (08) : 3793 - 3799
  • [9] Modernized Low Pressure Carbonylation Methods in Batch and Flow Employing Common Acids as a CO Source
    Brancour, Celia
    Fukuyama, Takahide
    Mukai, Yu
    Skrydstrup, Troels
    Ryu, Ilhyong
    [J]. ORGANIC LETTERS, 2013, 15 (11) : 2794 - 2797
  • [10] Pd-Catalyzed Thiocarbonylation with Stoichiometric Carbon Monoxide: Scope and Applications
    Burhardt, Mia N.
    Taaning, Rolf H.
    Skrydstrup, Troels
    [J]. ORGANIC LETTERS, 2013, 15 (04) : 948 - 951
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