Reactions in supercritical carbon dioxide (scCO2)

被引：0
作者：
Leitner, W [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
MODERN SOLVENTS IN ORGANIC SYNTHESIS | 1999年 / 206卷
关键词：
environmentally benign synthesis; catalysis; Green" solvents; supercritical fluids; carbon dioxide;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The present contribution highlights recent developments in the application of compressed (liquid or supercritical) carbon dioxide as a solvent for chemical reactions. After a brief introduction to the basic physical properties of scCO(2), some practical aspects of the use of compressed gases are discussed. A survey of successful applications of compressed and particularly supercritical CO2 in organic synthesis is provided with an emphasis on metal-catalyzed reactions.
引用
收藏
页码：107 / 132
页数：26
相关论文
共 100 条
  • [1] Anastas P. T., 1998, GREEN CHEM THEORY PR
  • [2] [Anonymous], 1999, CHEM SYNTHESIS SUPER
  • [3] [Anonymous], ANN CHIM PHYS
  • [4] Hydroformylation of hex-1-ene in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes
    Bach, I
    Cole-Hamilton, DJ
    [J]. CHEMICAL COMMUNICATIONS, 1998, (14) : 1463 - 1464
  • [5] BANET A, 1998, P 11 INT S HOM CAT S, P252
  • [6] Metalloporphyrin-catalyzed homogeneous oxidation in supercritical carbon dioxide
    Birnbaum, ER
    Le Lacheur, RM
    Horton, AC
    Tumas, W
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 139 (01) : 11 - 24
  • [7] Homogeneous organic reactions as mechanistic probes in supercritical fluids
    Brennecke, JF
    Chateauneuf, JE
    [J]. CHEMICAL REVIEWS, 1999, 99 (02) : 433 - 452
  • [8] ASYMMETRIC CATALYTIC-HYDROGENATION REACTIONS IN SUPERCRITICAL CARBON-DIOXIDE
    BURK, MJ
    FENG, SG
    GROSS, MF
    TUMAS, W
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (31) : 8277 - 8278
  • [9] Cacchi S, 1999, SYNLETT, P345
  • [10] Canelas DA, 1997, ADV POLYM SCI, V133, P103
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