Effects of Solvents on the Morphology and Conductivity of Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) Nanofibers

被引：45

作者：

Kara, Meryem O. Pehlivaner ^{[1
]}

Frey, Margaret W. ^{[1
]}

机构：

[1] Cornell Univ, Dept Fiber Sci & Apparel Design, Ithaca, NY 14853 USA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2014年 / 131卷 / 11期

基金：

美国国家科学基金会;

关键词：

conducting polymers; electrospinning; fibers; nanostructured polymers; ELECTRICAL-CONDUCTIVITY; ELECTROSPUN NANOFIBERS; POLY(3,4-ETHYLENEDIOXYTHIOPHENE)/POLY(4-STYRENE-SULFONATE); ENHANCEMENT;

D O I：

10.1002/app.40305

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this study, the effect of solvents on the morphology and conductivity of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS) nanofibers is investigated. Conductive PEDOT:PSS nanofibers are electrospun by dissolving a fiber-forming polymer, polyvinyl alcohol, in an aqueous dispersion of PEDOT:PSS. The conductivity of PEDOT:PSS nanofibers is enhanced 15-fold by addition of DMSO and almost 30-fold by addition of ethylene glycol to the spinning dopes. This improvement is attributed to the change in the conformation of the PEDOT chains from the coiled benzoid to the extended coil quinoid structure as confirmed by Raman spectroscopy, X-ray diffraction, and differential scanning calorimetry. Scanning electron microscopy images show that less beady and more uniform fiber morphology could be obtained by incorporation of ethylene glycol in the spinning dopes. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40305.

引用

页数：8

共 29 条

[1] Effects of solvent on carrier transport in poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) [J].

Ashizawa, S ;

Horikawa, R ;

Okuzaki, H .

SYNTHETIC METALS, 2005, 153 (1-3) :5-8

[2] Electric current rectification by an all-organic electrochemical device [J].

Chen, MX ;

Nilsson, D ;

Kugler, T ;

Berggren, M ;

Remonen, T .

APPLIED PHYSICS LETTERS, 2002, 81 (11) :2011-2013

[3] Studies of dopant effects in poly(3,4-ethylenedioxythiophene) using Raman spectroscopy [J].

Chiu, William W. ;

Travas-Sejdic, Jadranka ;

Cooney, Ralph P. ;

Bowmaker, Graham A. .

JOURNAL OF RAMAN SPECTROSCOPY, 2006, 37 (12) :1354-1361

[4] Polyethylenedioxythiophene coatings for humidity, temperature and strain sensing polyamide fibers [J].

Daoud, WA ;

Xin, JH ;

Szeto, YS .

SENSORS AND ACTUATORS B-CHEMICAL, 2005, 109 (02) :329-333

[5] Controlled deposition of electrospun poly(ethylene oxide) fibers [J].

Deitzel, JM ;

Kleinmeyer, JD ;

Hirvonen, JK ;

Tan, NCB .

POLYMER, 2001, 42 (19) :8163-8170

[6] PEDOT:PSS films-Effect of organic solvent additives and annealing on the film conductivity [J].

Dimitriev, O. P. ;

Grinko, D. A. ;

Noskov, Yu. V. ;

Ogurtsov, N. A. ;

Pud, A. A. .

SYNTHETIC METALS, 2009, 159 (21-22) :2237-2239

[7] Manipulated Electrospun PVA Nanofibers with Inexpensive Salts [J].

Ding, Wei ;

Wei, Suying ;

Zhu, Jiahua ;

Chen, Xuelong ;

Rutman, Dan ;

Guo, Zhanhu .

MACROMOLECULAR MATERIALS AND ENGINEERING, 2010, 295 (10) :958-965

[8] Polymer nanofibers assembled by electrospinning [J].

Frenot, A ;

Chronakis, IS .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2003, 8 (01) :64-75

[9] Characterization of the PEDOT-PSS system by means of X-ray and ultraviolet photoelectron spectroscopy [J].

Greczynski, G ;

Kugler, T ;

Salaneck, WR .

THIN SOLID FILMS, 1999, 354 (1-2) :129-135

[10] Structure and morphology of freeze/thawed PVA hydrogels [J].

Hassan, CM ;

Peppas, NA .

MACROMOLECULES, 2000, 33 (07) :2472-2479

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