Hollow Fe-containing carbon fibers with tubular tertiary structure: preparation and Li-storage properties

被引：28

作者：

Adelhelm, Philipp ^{[2
]}

Hu, Yong-Sheng ^{[1
,4
]}

Antonietti, Markus ^{[3
]}

Maier, Joachim ^{[4
]}

Smarsly, Bernd M. ^{[5
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China

[2] Univ Utrecht, Debye Inst NanoMat Sci, NL-3584 CA Utrecht, Netherlands

[3] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

[4] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

[5] Univ Giessen, Inst Phys Chem, D-35390 Giessen, Germany

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2009年 / 19卷 / 11期

关键词：

ELECTRODE MATERIALS; HYDROGEN STORAGE; THERMAL-DECOMPOSITION; NANOTUBES; NANOFIBERS; PERFORMANCE; PLATINUM; CATALYST; COMPOSITES; FILAMENTS;

D O I：

10.1039/b818452f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hollow carbon fibers with a defined tubular cross-section were obtained by simply heating poly(styrene) in the presence of iron salts. The structures possess a high content of mesoporosity and macroporosity. The carbon itself is characterized by a well-developed sp(2)-graphene structure. When used as anode material in lithium ion batteries, a remarkably high reversible capacity as high as 860 mAh/g was observed, which is attributed to both the morphology of the carbon and the incorporation of iron species.

引用

页码：1616 / 1620

页数：5

共 38 条

[1] Generation of hierarchical meso- and macroporous carbon from mesophase pitch by spinodal decomposition using polymer templates [J].

Adelhelm, Philipp ;

Hu, Yong-Sheng ;

Chuenchom, Laemthong ;

Antonietti, Markus ;

Smarsly, Bernd M. ;

Maier, Joachim .

ADVANCED MATERIALS, 2007, 19 (22) :4012-+

[2] Nanotechnology - How does a nanofibre grow? [J].

Ajayan, PM .

NATURE, 2004, 427 (6973) :402-403

[3] Nanostructured materials for advanced energy conversion and storage devices [J].

Aricò, AS ;

Bruce, P ;

Scrosati, B ;

Tarascon, JM ;

Van Schalkwijk, W .

NATURE MATERIALS, 2005, 4 (05) :366-377

[4] Synthesis of carbon nanotubes from bulk polymer [J].

Cho, WS ;

Hamada, E ;

Kondo, Y ;

Takayanagi, K .

APPLIED PHYSICS LETTERS, 1996, 69 (02) :278-279

[5] Iron-carbon composites as electrode materials in lithium batteries [J].

Concheso, A. ;

Santamaria, R. ;

Menendez, R. ;

Jimenez-Mateos, J. M. ;

Alcantara, R. ;

Lavela, P. ;

Tirado, J. L. .

CARBON, 2006, 44 (09) :1762-1772

[6] Carbon nanofibers: Catalytic synthesis and applications [J].

De Jong, KP ;

Geus, JW .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2000, 42 (04) :481-510

[7] Nanostructured Sn-C composite as an advanced anode material in high-performance lithium-ion batteries [J].

Derrien, Gaelle ;

Hassoun, Jusef ;

Panero, Stefania ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2007, 19 (17) :2336-+

[8] Platinum and platinum-ruthenium nanoparticles supported on ordered mesoporous carbon and their electrocatalytic performance for fuel cell reactions [J].

Ding, J ;

Chan, KY ;

Ren, JW ;

Xiao, FS .

ELECTROCHIMICA ACTA, 2005, 50 (15) :3131-3141

[9] High-rate, long-life Ni-Sn nanostructured electrodes for lithium-ion batteries [J].

Hassoun, Jusef ;

Panero, Stefania ;

Simon, Patrice ;

Taberna, Pierre Louis ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2007, 19 (12) :1632-+

[10] Atomic-scale imaging of carbon nanofibre growth [J].

Helveg, S ;

López-Cartes, C ;

Sehested, J ;

Hansen, PL ;

Clausen, BS ;

Rostrup-Nielsen, JR ;

Abild-Pedersen, F ;

Norskov, JK .

NATURE, 2004, 427 (6973) :426-429

← 1 2 3 4 →