Recyclable self-assembly-supported catalyst for chelation-assisted hydroacylation of an olefin with a primary alcohol

被引：31

作者：

Kim, Do-Won ^{[1
]}

Lim, Sung-Gon ^{[1
]}

Jun, Chul-Ho ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 14期

关键词：

D O I：

10.1021/ol0608045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel recyclable catalyst for chelation-assisted hydroacylation of an olefin with a primary alcohol was developed by utilizing a hydrogen-bonding self-assembly motif consisting of a barbiturate bearing 2-aminopyridin-4-yl group and 5-hexyl-2,4,6-triaminopyrimidine. This was further applied to a mixed catalyst system to recycle both organic and organometallic catalysts.

引用

收藏

页码：2937 / 2940

页数：4

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