InCl3/SiO2-catalyzed α-amination of 1,3-dicarbonyl compounds under microwave irradiation

被引：11

作者：

Yadav, JS ^{[1
]}

Reddy, BVS ^{[1
]}

Venugopal, C ^{[1
]}

Padmavani, B ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 40期

关键词：

alpha-amination; azocarboxylate; microwave; alpha-hydrazino ketones;

D O I：

10.1016/j.tetlet.2004.07.156

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of 1,3-dicarbonyl compounds undergo smooth alpha-amination with diethyl azodicarboxylate (DEAD) on the surface of silica gel impregnated with indium trichloride under microwave irradiation and solvent-free conditions. Improved yields and enhanced reaction rates were observed. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：7507 / 7509

页数：3

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