Structural and vibrational studies of LiNi1-yCoyVO4 (0≤y≤1) cathodes materials for Li-ion batteries

被引：63
作者：
Julien, C
Massot, M
Pérez-Vicente, C
机构：
[1] Univ Paris 06, UMR7603, Lab Milieux Desordonnes & Heterogenes, F-75252 Paris 05, France
[2] Univ Montpellier 2, Lab Agregats Mol & Mat Inorgan, F-34095 Montpellier 5, France
来源：
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2000年 / 75卷 / 01期
关键词：
lithium vanadates; lithium batteries; Raman scattering; FTIR; Rietveld refinement;
D O I：
10.1016/S0921-5107(99)00601-7
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The structure and vibrational properties of high voltage cathode materials, namely LiNi1-xCOyVO4 solid solution with (0 less than or equal to y less than or equal to 1), have been studied using X-ray diffraction, Raman scattering and FTIR measurements. Rietveld refinements show that LiNi1-yCoyVO4 vanadates belong to the inverse spinel structure with Fd (3) over bar m(O-h(7)) space group. Analysis of Raman spectra has been carried out in the molecular approximation using a local environment model including VO4 tetrahedra, (Ni. Co)O-6 and LiO6 octahedra as vibrational local units. (C) 2000 Elsevier Science S.A. All lights reserved.
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页码：6 / 12
页数：7
相关论文
共 26 条
  • [11] The effects of the stoichiometry and synthesis temperature on the preparation of the inverse spinel LiNiVO4 and its performance as a new high voltage cathode material
    Fey, GTK
    Dahn, JR
    Zhang, MJ
    Li, W
    [J]. JOURNAL OF POWER SOURCES, 1997, 68 (02) : 549 - 552
  • [12] New inverse spinel cathode materials for rechargeable lithium batteries
    Fey, GTK
    Wang, KS
    Yang, SM
    [J]. JOURNAL OF POWER SOURCES, 1997, 68 (01) : 159 - 165
  • [13] FEY GTK, 1996, 8 INT M LITH BATT, P143
  • [14] FEY GTK, 1994, Patent No. 8243393
  • [15] FEY GTK, 1996, 8 INT M LITH BATT, P426
  • [16] STRUCTURE AND MAGNETIC-PROPERTIES OF LIMVO4 (M=CO, NI, CU) SPINELS
    GONZALEZ, C
    GAITAN, M
    LOPEZ, ML
    VEIGA, ML
    SAEZPUCHE, R
    PICO, C
    [J]. JOURNAL OF MATERIALS SCIENCE, 1994, 29 (13) : 3458 - 3460
  • [17] *JCPDS, 381395 JCPDS INT CTR
  • [18] Vibrational Spectroscopy of Lithium Manganese Spinel Oxides
    Julien, C.
    Rougier, A.
    Haro-Poniatowski, E.
    Nazri, G. A.
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1998, 311 : 81 - 87
  • [19] Julien C, 1998, MATER RES SOC SYMP P, V496, P415
  • [20] NAZRI M, 1998, 193 M EL SOC SAN DIE, V981, P48
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