Association of bromate ion in nonaqueous solutions of alkali metal salts

被引：0
|
作者：
Mikhailov, G. P. [1 ]
Rabchuk, L. V. [1 ]
Lazarev, V. V. [1 ]
机构：
[1] Ufa State Aviat Tech Univ, Ufa 450000, Bashkortostan, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 04期
关键词：
SPECTRA; RAMAN;
D O I：
10.1134/S003602361704012X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Manifestations of ion association of lithium cation with BrO3 (-) ion in the vibrational spectrum have been studied by IR spectroscopy. The microstructure of the bromate ion with lithium cation in a contact ion pair in an aprotic solvent has been determined by the density functional theory method in the B3LYP/cc-pVTZ approximation, and the vibrational spectrum of coordinated bromate ion has been calculated.
引用
收藏
页码：523 / 526
页数：4
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