Association of bromate ion in nonaqueous solutions of alkali metal salts

被引：0

作者：

Mikhailov, G. P. ^{[1
]}

Rabchuk, L. V. ^{[1
]}

Lazarev, V. V. ^{[1
]}

机构：

[1] Ufa State Aviat Tech Univ, Ufa 450000, Bashkortostan, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 04期

关键词：

SPECTRA; RAMAN;

D O I：

10.1134/S003602361704012X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Manifestations of ion association of lithium cation with BrO3 (-) ion in the vibrational spectrum have been studied by IR spectroscopy. The microstructure of the bromate ion with lithium cation in a contact ion pair in an aprotic solvent has been determined by the density functional theory method in the B3LYP/cc-pVTZ approximation, and the vibrational spectrum of coordinated bromate ion has been calculated.

引用

页码：523 / 526

页数：4

共 15 条

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