Sulfuric acid-functionalized mesoporous benzene-silica with a molecular-scale periodicity in the walls

被引:310
作者
Yang, QH
Kapoor, MP
Inagaki, S
机构
[1] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan
[2] JST, CREST, Nagakute, Aichi 4801192, Japan
关键词
D O I
10.1021/ja026799r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel sulfuric acid-functionalized mesoporous benzene-silicas with a molecular-scale periodicity in the walls were derived from the mesoporous benzene-silica possessing mercaptopropyl groups by the oxidative transformation of -SH into -SO3H. Copyright © 2002 American Chemical Society.
引用
收藏
页码:9694 / 9695
页数:2
相关论文
共 18 条
[1]   Periodic mesoporous organosilicas with organic groups inside the channel walls [J].
Asefa, T ;
MacLachlan, MJ ;
Coombs, N ;
Ozin, GA .
NATURE, 1999, 402 (6764) :867-871
[2]   Novel bifunctional periodic mesoporous organosilicas, BPMOs: Synthesis, characterization, properties and in-situ selective hydroboration-alcoholysis reactions of functional groups [J].
Asefa, T ;
Kruk, M ;
MacLachlan, MJ ;
Coombs, N ;
Grondey, H ;
Jaroniec, M ;
Ozin, GA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (35) :8520-8530
[3]   Structure and chain dynamics of alkanethiol-capped gold colloids [J].
Badia, A ;
Gao, W ;
Singh, S ;
Demers, L ;
Cuccia, L ;
Reven, L .
LANGMUIR, 1996, 12 (05) :1262-1269
[4]   Direct synthesis of periodic mesoporous organosilicas: Functional incorporation by co-condensation with organosilanes [J].
Burleigh, MC ;
Markowitz, MA ;
Spector, MS ;
Gaber, BP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (41) :9935-9942
[5]   Functionalized monolayers on ordered mesoporous supports [J].
Feng, X ;
Fryxell, GE ;
Wang, LQ ;
Kim, AY ;
Liu, J ;
Kemner, KM .
SCIENCE, 1997, 276 (5314) :923-926
[6]   Cubic hybrid organic-inorganic mesoporous crystal with a decaoctahedral shape [J].
Guan, S ;
Inagaki, S ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (23) :5660-5661
[7]   An ordered mesoporous organosilica hybrid material with a crystal-like wall structure [J].
Inagaki, S ;
Guan, S ;
Ohsuna, T ;
Terasaki, O .
NATURE, 2002, 416 (6878) :304-307
[8]   Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks [J].
Inagaki, S ;
Guan, S ;
Fukushima, Y ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9611-9614
[9]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[10]   Synthesis of ordered microporous silicates with organosulfur surface groups and their applications as solid acid catalysts [J].
Lim, MH ;
Blanford, CF ;
Stein, A .
CHEMISTRY OF MATERIALS, 1998, 10 (02) :467-+