Study on material removal mechanism in ultrasonic chemical assisted polishing of silicon carbide

被引:30
作者
Chen, Xin
Liang, Yingdong
Cui, Zhijie
Meng, Fanwei
Zhang, Chao
Chen, Liaoyuan
Yu, Tianbiao [1 ]
Zhao, Ji [1 ]
机构
[1] Northeastern Univ, Sch Mech Engn & Automation, Shenyang 110819, Peoples R China
关键词
Ultrasonic chemical assisted polishing; Fenton reaction; Ultrasonic vibration; Hydroxyl radical; Silicon carbide; SINGLE-CRYSTAL DIAMOND; ADVANCED OXIDATION PROCESSES; HYDROGEN-PEROXIDE; FENTONS REAGENT; 100; SUBSTRATE; DEGRADATION; MIRROR; WAFER; IONS; XPS;
D O I
10.1016/j.jmapro.2022.11.014
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An ultrasonic chemical assisted polishing (UCAP) method exploiting the recombination mechanism of ultrasonic vibration, Fenton oxidation and mechanical impact is proposed for efficient finishing of silicon carbide (SiC). Experiments and theoretical analyses were performed to explore the effect of H2O2 content, FeSO4 content and ultrasonic amplitude on removal rate and surface roughness of UCAP and material removal mechanism. The combined interactions of ultrasonic and Fenton oxidation achieved superior polished efficiency and quality with a 19.51 % improvement in MRR and a 18.3 % increase in Ra compared to MP. This originates from the syn-ergistic effect of oxidation of center dot OH generated by chemical polishing slurry and the promotion of mechanical removal of abrasives and oxidation rate of SiC by ultrasonic vibration. Excessive FeSO4 and insufficient H2O2 can induce flocculent precipitates, thus reducing the MRR of SiC UCAP. Moreover, a larger ultrasonic amplitude generated a greater MRR, but with a smaller deterioration of the machined surface. This investigation reveals that UCAP is a progressive precision machining approach for optical ceramic materials polishing. The proposed polishing process will promote hybrid processing technologies research and simplify the existing SiC machining process to achieve extremely efficient polishing of SiC.
引用
收藏
页码:1463 / 1477
页数:15
相关论文
共 56 条
[1]   Silicon carbide deformable mirror with 37 actuators for adaptive optics [J].
Ahn, Kyohoon ;
Rhee, Hyug-Gyo ;
Yang, Ho-Soon ;
Kihm, Hagyong .
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2015, 67 (10) :1882-1888
[2]  
[Anonymous], 2004, Advanced oxidation processes for water and wastewater treatment
[3]   A review on Fenton and improvements to the Fenton process for wastewater treatment [J].
Babuponnusami, Arjunan ;
Muthukumar, Karuppan .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2014, 2 (01) :557-572
[4]   XPS analysis of nanostructured materials and biological surfaces [J].
Baer, D. R. ;
Engelhard, M. H. .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2010, 178 :415-432
[5]   Parametric study on the effect of the ratios [H2O2]/[Fe3+] and [H2O2]/[substrate] on the photo-Fenton degradation of ationic azo dye Basic Blue 41 [J].
Bouafia-Chergui, Souad ;
Oturan, Nihal ;
Khalaf, Hussein ;
Oturan, Mehmet A. .
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2010, 45 (05) :622-629
[6]   Electro-Fenton Process and Related Electrochemical Technologies Based on Fenton's Reaction Chemistry [J].
Brillas, Enric ;
Sires, Ignasi ;
Oturan, Mehmet A. .
CHEMICAL REVIEWS, 2009, 109 (12) :6570-6631
[7]   CRITICAL-REVIEW OF RATE CONSTANTS FOR REACTIONS OF HYDRATED ELECTRONS, HYDROGEN-ATOMS AND HYDROXYL RADICALS (.OH/.O-) IN AQUEOUS-SOLUTION [J].
BUXTON, GV ;
GREENSTOCK, CL ;
HELMAN, WP ;
ROSS, AB .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1988, 17 (02) :513-886
[8]  
Chen Z., 2011, TIANJIN MET, V5, P49, DOI [10.3969/j.issn.1006-110X.2011.05.018, DOI 10.3969/J.ISSN.1006-110X.2011.05.018]
[9]   The mechanism of Fenton reaction of hydrogen peroxide with single crystal 6H-SiC substrate [J].
Deng, Jiayun ;
Pan, Jisheng ;
Zhang, Qixiang ;
Yan, Qiusheng ;
Lu, Jiabin .
SURFACES AND INTERFACES, 2020, 21
[10]  
Deny P., 2005, Proceedings of the SPIE - The International Society for Optical Engineering, V5868, DOI 10.1117/12.617226