Comparison of the bond lengths for the lanthanide complexes of tripodal heptadentate ligands

被引：26

作者：

Kanesato, M ^{[1
]}

Mizukami, S ^{[1
]}

Houjou, H ^{[1
]}

Tokuhisa, H ^{[1
]}

Koyama, E ^{[1
]}

Nagawa, Y ^{[1
]}

机构：

[1] AIST, Nanoarchitect Res Ctr, Tsukuba, Ibaraki 3058562, Japan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2004年 / 374卷 / 1-2期

关键词：

lanthanide complexes; yttrium complexes; crystal structures; tripodal ligand; bond lengths for complexes;

D O I：

10.1016/j.jallcom.2003.11.096

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation and characterization of Ln(III) complexes (Ln = Sm, Yb) of tripodal heptadentate ligand trensal, tris[2-(saticylideneamino) ethyl]amine (H3L(1)) have been studied. The molecular structures of [LnL(1)] were determined by X-ray structural analysis; these are heptadentate complexes in which the metal ions are coordinated by the three oxygen atoms and the four nitrogen atoms. [LnL(1)] is a novel example because the coordination number is seven in the wide range of the series of [LnL(1)] (Ln = Y, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, Lu). This has made it possible to compare the bond lengths for the lanthanide and yttrium complexes under the same coordination number. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：307 / 310

页数：4

共 50 条

[21] SOME COPPER(I) AND COPPER(II) COMPLEXES OF 2 NEW POTENTIALLY HEPTADENTATE TRIPODAL SCHIFF-BASE LIGANDS
ALYEA, EC
FERGUSON, G
JENNINGS, M
LI, BL
XU, Z
YOU, XZ
LIU, SX
POLYHEDRON, 1990, 9 (20) : 2463 - 2467
[22] Trigonal (-3) symmetry octahedral lanthanide(III) complexes of zwitterionic tripodal ligands: luminescence and magnetism
Janzen, Daron E.
Juchum, Michael
Presow, Shaun R.
Ronson, Tanya K.
Mohr, Wolfgang
Clerac, Rodolphe
Feltham, Humphrey L. C.
Brooker, Sally
SUPRAMOLECULAR CHEMISTRY, 2016, 28 (1-2) : 125 - 140
[23] Lanthanide complexes containing tripodal oxygen ligand
Yuen, Pong K.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
[24] Solid-state and solution properties of cationic lanthanide complexes of a new neutral heptadentate N4O3 tripodal ligand
Bravard, F
Bretonniére, Y
Wietzke, F
Gateau, C
Mazzanti, M
Delangle, P
Pécaut, J
INORGANIC CHEMISTRY, 2003, 42 (24) : 7978 - 7989
[25] Group 13 and lanthanide complexes supported by tridentate tripodal triamine ligands: Structural diversity and polymerization catalysis
Zhu, Hongping
Chen, Eugene Y. A.
ORGANOMETALLICS, 2007, 26 (22) : 5395 - 5405
[26] Syntheses, crystal structures, and luminescent properties of lanthanide complexes with tripodal ligands bearing benzimidazole and pyridine groups
Yang, XP
Kang, BS
Wong, WK
Su, CY
Liu, HQ
INORGANIC CHEMISTRY, 2003, 42 (01) : 169 - 179
[27] Tripodal heptadentate amine ligands with different nitrogen substituents for SARA- and photo-ATRP
Xu, Xiaoling
Wang, Tianheng
Li, Die
Bao, Chunyang
Wang, Yan
Zhang, Jingyu
Peng, Bin
Hong, Mei
Chen, Jing
Zhang, Qiang
EUROPEAN POLYMER JOURNAL, 2022, 170
[28] LANTHANIDE COMPLEXES OF COMPARTMENTAL LIGANDS
ABID, KK
FENTON, DE
INORGANICA CHIMICA ACTA-F-BLOCK ELEMENTS ARTICLES AND LETTERS, 1985, 109 (01): : L5 - L7
[29] Lanthanide Complexes of Compartmental Ligands
Abid, Khalil K.
Fenton, David E.
INORGANICA CHIMICA ACTA, 1984, 94 (1-3) : 73 - 74
[30] Investigation of Chromium Complexes with a Series of Tripodal Ligands
Schaefer, Sabrina
Becker, Jonathan
Beitat, Alexander
Wuertele, Christian
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (12-13): : 2269 - 2275

← 1 2 3 4 5 →