Synthesis and crystal structure of Ag2(admtrz)2(CF3CO2)2 (admtrz=4-amino-3, 5-dimethyl-1, 2, 4-triazole)

被引：0
作者：
Liu, JC [1 ]
Guo, GC [1 ]
Ma, HW [1 ]
Yang, C [1 ]
Zhou, GW [1 ]
Zheng, FK [1 ]
Lin, SH [1 ]
Wang, MS [1 ]
Huang, JS [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2002年 / 21卷 / 04期
关键词：
synthesis; silver; 4-amino-3; 5-dimethyl-1; 2; 4-triazole; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound (Ag2F6O4N8C12H16, M-r= 666.07) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Fddd with cell parameters: a = 12.2718(1), b = 23.3229(1), c = 29.1918(1) Angstrom, V = 8355.10(8) Angstrom(3), Z = 16, D-c = 2.118 g/cm(3), F(000) = 5184 and p = 1.966 mm(-1). The structure was solved by direct methods and refined by full-matrix least-squares methods. The final R = 0.0624 and Rw = 0.1699 for 1584 observed reflections with I greater than or equal to 2.0sigma(I). The molecular structure consists of two trigonal silver atoms bridged by double triazole ligands. The distance between the two silver atoms Ag(1)...Ag(1A) is 3.475(2) Angstrom.
引用
收藏
页码：371 / 373
页数：3
相关论文
共 50 条
  • [31] Synthesis and characterization of Ag(I) salts with diethylenetriamine.: Crystal structure of [Ag2(dien)2](ClO4)2
    Zhu, HL
    Wang, XJ
    Liu, XY
    Wang, DQ
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2003, 33 (08): : 1417 - 1424
  • [32] Synthesis improvement for 4, 4'-azobis (1, 2, 4-triazole)
    Xue, Lin-Jun
    Tang, Zhan
    Bi, Yan-Gang
    Rong, Jing-Jing
    Yang, Li
    Zhang, Tong-Lai
    Hanneng Cailiao/Chinese Journal of Energetic Materials, 2015, 23 (05): : 420 - 423
  • [33] Crystal structure and computed properties of a coordination compound [Zn(ATZ)2(N3)2]3(H2O)2 (ATZ=4-Amino-1,2,4-triazole)
    Xue, Rui
    Song, Jun-Hui
    MAIN GROUP CHEMISTRY, 2016, 15 (03) : 287 - 294
  • [34] Synthesis and Crystal Structure of a Manganese Complex with 3-Methyl-4-(p-bromophenyl)-5-(2-pyridyl)-1,2,4-triazole
    Zhao Jian
    Lu Wei
    Chen Lang
    Shen Xuan
    Xu Yan
    Zhu Dun-Ru
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (04) : 743 - 746
  • [35] A novel energetic material hydrazinium 3, 5-dinitroamino-1, 2, 4-triazole: synthesis and properties
    Zhou, Cheng
    Wang, Bo-Zhou
    Huo, Huan
    Zhou, Qun
    Yang, Wei
    Ye, Zhi-Hu
    Hanneng Cailiao/Chinese Journal of Energetic Materials, 2014, 22 (04): : 576 - 578
  • [36] Synthesis and crystal structure of Cu(11) complex with 4-(pyridyl-2)-1,2,4-triazole
    Shakirova, OG
    Virovets, AV
    Naumov, DY
    Shvedenkov, YG
    Elokhina, VN
    Lavrenova, LG
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (09) : 690 - 693
  • [37] Synthesis and Structures of Silver(I) Adducts with 4-Amino-3,5-diisobutyl-4H-1,2,4-triazole: The Identification of a New Type of Ag3tz6 Cluster
    Zhan-Dong Huang
    Jun-Xian Chen
    De-Liang Wang
    Guang Yang
    Journal of Cluster Science, 2013, 24 : 61 - 71
  • [38] Synthesis and characterization of oligo-salicylidene-3-amino-1,2,4-triazole and oligo-2-hydroxy naphthalidene-3-amino-1,2,4-triazole
    Erçag, A
    Kaya, I
    Senol, D
    Koyuncu, S
    POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2005, 44 (02) : 265 - 274
  • [39] Synthesis and Structure of a Ladder-like Co-crystal Cu~ICl with 3,5-Dipropyl-4-amino-1,2,4-triazole
    闫娟枝
    卢丽萍
    苏峰
    朱苗力
    结构化学, 2015, 34 (03) : 401 - 407
  • [40] Crystal structure and quantum chemical investigation of 4-(3,4-dichlorphenyl)-1,2,4-triazole
    Virovets, A. V.
    Lider, E. V.
    Elokhina, V. N.
    Bushuev, M. B.
    Lavrenova, L. G.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (02) : 358 - 362
12345