Synthesis and crystal structure of Ag2(admtrz)2(CF3CO2)2 (admtrz=4-amino-3, 5-dimethyl-1, 2, 4-triazole)

被引：0
|
作者：
Liu, JC [1 ]
Guo, GC [1 ]
Ma, HW [1 ]
Yang, C [1 ]
Zhou, GW [1 ]
Zheng, FK [1 ]
Lin, SH [1 ]
Wang, MS [1 ]
Huang, JS [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2002年 / 21卷 / 04期
关键词：
synthesis; silver; 4-amino-3; 5-dimethyl-1; 2; 4-triazole; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound (Ag2F6O4N8C12H16, M-r= 666.07) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Fddd with cell parameters: a = 12.2718(1), b = 23.3229(1), c = 29.1918(1) Angstrom, V = 8355.10(8) Angstrom(3), Z = 16, D-c = 2.118 g/cm(3), F(000) = 5184 and p = 1.966 mm(-1). The structure was solved by direct methods and refined by full-matrix least-squares methods. The final R = 0.0624 and Rw = 0.1699 for 1584 observed reflections with I greater than or equal to 2.0sigma(I). The molecular structure consists of two trigonal silver atoms bridged by double triazole ligands. The distance between the two silver atoms Ag(1)...Ag(1A) is 3.475(2) Angstrom.
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页码：371 / 373
页数：3
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