Emergence of charge density wave domain walls above the superconducting dome in 1T-TiSe2

Superconductivity in so-called unconventional superconductors is nearly always found in the vicinity of another ordered state, such as antiferromagnetism, charge density wave (CDW), or stripe order. This suggests a fundamental connection between superconductivity and fluctuations in some other order parameter. To better understand this connection, we used high-pressure X-ray scattering to directly study the CDW order in the layered dichalcogenide TiSe2, which was previously shown to exhibit superconductivity when the CDW is suppressed by pressure(1) or intercalation of Cu atoms(2). We succeeded in suppressing the CDW fully to zero temperature, establishing for the first time the existence of aquantum critical point (QCP) at P-c = 5.1 +/- 0.2 GPa, which is more than 1 GPa beyond the end of the superconducting region. Unexpectedly, at P = 3 GPa we observed a reentrant, weakly first order, incommensurate phase, indicating the presence of a Lifshitz tricritical point somewhere above the superconducting dome. Our study suggests that superconductivity in TiSe2 may not be connected to the QCP itself, but to the formation of CDW domain walls.