Development of dilutable green nanoemulsions for removal of Eriochrome black T from aqueous solution and optimization by Box-Behnken design

被引：14

作者：

Shakeel, Faiyaz ^{[1
]}

Haq, Nazrul ^{[1
]}

Alanazi, Fars K. ^{[1
,2
]}

Alsarra, Ibrahim A. ^{[1
,2
]}

机构：

[1] King Saud Univ, Ctr Excellence Biotechnol Res, Riyadh 11451, Saudi Arabia

[2] King Saud Univ, Coll Pharm, Dept Pharmaceut, Kayyali Chair Pharmaceut Ind, Riyadh 11451, Saudi Arabia

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2014年 / 196卷

关键词：

Adsorption; Box-Behnken design; Eriochrome black T; Green nanoemulsion; Optimization; FORMULATION; BIOAVAILABILITY; DEGRADATION; CHROMIUM; SYSTEM; WATER;

D O I：

10.1016/j.molliq.2014.04.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In present study, attempts were made to develop green nanoemulsions for removal of Eriochrome black T (EBT) from its aqueous solution. Box-Behnken design was applied for optimization of nanoemulsion compositions for maximum removal of EBT. Adsorption studies were performed for contact time of 10, 15 and 20 min by mixing small amounts of concentrated green nanoemulsions with relatively large amounts of bulk aqueous solution of EBT. Droplet size, viscosity and % removal were significantly influenced by ethyl acetate & surfactant concentrations and contact time had negligible/little impact on these parameters. Based on lowest droplet size (13.8 nm), lowest viscosity (10.9 cp) and highest % EBT removal efficiency (99.6%), the nanoemulsion N-9 was optimized as the best formulation for removal of EBT. These results indicated that nanoemulsions could be applied successfully for the removal of toxic dyes such as EBT from its aqueous solution via liquid-liquid adsorption. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：340 / 347

页数：8

共 30 条

[1] Amenaghawon N. A., 2012, Environment and Natural Resources Research, V2, P73
[2] Amenaghawon N. A., 2013, British Biotechnology Journal, V3, P236
[3] SMEDDS of Glyburide: Formulation, In Vitro Evaluation, and Stability Studies
Bachhav, Yogeshwar G.
Patravale, Vandana B.
[J]. AAPS PHARMSCITECH, 2009, 10 (02): : 482 - 487
[4] Optimization of cloud point extraction and solid phase extraction methods for speciation of arsenic in natural water using multivariate technique
Baig, Jameel A.
Kazi, Tasneem G.
Shah, Abdul Q.
Arain, Mohammad B.
Afridi, Hassan I.
Kandhro, Ghulam A.
Khan, Sumaira
[J]. ANALYTICA CHIMICA ACTA, 2009, 651 (01) : 57 - 63
[5] The effect of UV radiation absorption of cationic and anionic dye solutions on their photocatalytic degradation in the presence TiO2
Baran, Wojciech
Makowski, Andrzej
Wardas, Wladyslaw
[J]. DYES AND PIGMENTS, 2008, 76 (01) : 226 - 230
[6] Removal of Methylene Blue and Eriochrome Black T from aqueous solutions by biosorption on Scolymus hispanicus L.: Kinetics, equilibrium and thermodynamics
Barka, Noureddine
Abdennouri, Mohammed
El Makhfouk, Mohammed
[J]. JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2011, 42 (02) : 320 - 326
[7] Acid hydrolysis of corn stover for biohydrogen production using Thermoanaerobacterium thermosaccharolyticum W16
Cao, Guangli
Ren, Nanqi
Wang, Aijie
Lee, Duu-Jong
Guo, Wanqian
Liu, Bingfeng
Feng, Yujie
Zhao, Qingliang
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (17) : 7182 - 7188
[8] Release modulating hydrophilic matrix systems of losartan potassium: Optimization of formulation using statistical experimental design
Chopra, Shruti
Patil, Gayathri V.
Motwani, Sanjay K.
[J]. EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS, 2007, 66 (01) : 73 - 82
[9] The use of microemulsions to remove chromium from industrial sludge
Dantas, T. N. Castro
Oliveira, K. R.
Dantas Neto, A. A.
Moura, M. C. P. A.
[J]. WATER RESEARCH, 2009, 43 (05) : 1464 - 1470
[10] Heavy metals extraction by microemulsions
Dantas, TNC
Neto, AAD
Moura, MCPA
Neto, ELB
Forte, KR
Leite, RHL
[J]. WATER RESEARCH, 2003, 37 (11) : 2709 - 2717

← 1 2 3 →