Hypericin, hypocrellin, and model compounds: Primary photoprocesses of light-induced antiviral agents

被引:65
作者
English, DS [1 ]
Das, K [1 ]
Zenner, JM [1 ]
Zhang, W [1 ]
Kraus, GA [1 ]
Larock, RC [1 ]
Petrick, JW [1 ]
机构
[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011
关键词
D O I
10.1021/jp963046g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The excited-state photophysics of the light-induced antiviral agents hypericin and hypocrellin are compared with those of the hexa- and tetramethoxy analogues of hypericin. The results are consistent with the interpretation of the primary photoprocess in hypericin and hypocrellin as that of excited-state intramolecular proton or atom transfer.
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页码:3235 / 3240
页数:6
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