Synthesis of Aryl Trimethylstannanes from Aryl Amines: A Sandmeyer-Type Stannylation Reaction

被引：83

作者：

Qiu, Di ^{[1
,2
]}

Meng, He ^{[1
,2
]}

Jin, Liang ^{[1
,2
]}

Wang, Shuai ^{[1
,2
]}

Tang, Shengbo ^{[1
,2
]}

Wang, Xi ^{[1
,2
]}

Mo, Fanyang ^{[1
,2
]}

Zhang, Yan ^{[1
,2
]}

Wang, Jianbo ^{[1
,2
,3
]}

机构：

[1] Peking Univ, Coll Chem, Minist Educ, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China

[2] Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 44期

关键词：

aryl stannanes; cross-coupling; diazonium salts; Sandmeyer reaction; Stille coupling reaction; CROSS-COUPLING REACTIONS; METAL-FREE BORYLATION; ORGANIC HALIDES; ORGANOTIN COMPOUNDS; DIRECT CONVERSION; RADICAL-ADDITION; DIAZONIUM SALTS; ALKYL NITRITES; PALLADIUM; ARYLAMINES;

D O I：

10.1002/anie.201304579

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for C-C bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer-type transformation using aromatic amines as the starting materials is described. DCE: 1,2-dichloroethane. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11581 / 11584

页数：4

共 58 条

[1] Design and Synthesis of Skeletal Analogues of Gambierol: Attenuation of Amyloid-β and Tau Pathology with Voltage-Gated Potassium Channel and N-Methyl-D-aspartate Receptor Implications [J].