Dynamic Strengthening of Carbon Nanotube Fibers under Extreme Mechanical Impulses

被引:38
作者
Xie, Wanting [1 ,2 ]
Zhang, Runyang [3 ]
Headrick, Robert J. [4 ,5 ]
Taylor, Lauren W. [5 ]
Kooi, Steven [6 ]
Pasquali, Matteo [4 ,5 ]
Muftu, Sinan [3 ]
Lee, Jae-Hwang [1 ]
机构
[1] Univ Massachusetts, Dept Mech & Ind Engn, Amherst, MA 01003 USA
[2] Univ Massachusetts, Dept Phys, Amherst, MA 01003 USA
[3] Northeastern Univ, Dept Mech & Ind Engn, Boston, MA 02139 USA
[4] Rice Univ, Dept Chem, Houston, TX 77005 USA
[5] Rice Univ, Dept Chem & Biomol Engn, Houston, TX 77005 USA
[6] MIT, Inst Soldier Nanotechnol, Cambridge, MA 02139 USA
关键词
Nanomaterial armor; microballistics; high-strain-rate hardening; collective friction; impact delocalization; HIGH-PERFORMANCE; FAILURE MECHANISMS; BALLISTIC IMPACT; BEHAVIOR; SILK; KEVLAR-29; GRAPHENE;
D O I
10.1021/acs.nanolett.9b00350
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A monofilament fiber spun from individual carbon nanotubes is an arbitrarily long ensemble of weakly interacting, aligned, discrete nanoparticles. Despite the structural resemblance of carbon nanotube monofilament fibers to crystalline polymeric fibers, very little is known about their dynamic collective mechanics, which arise from van der Waals interactions among the individual carbon nanotubes. Using ultrafast stroboscopic microscopy, we study the collective dynamics of carbon nanotube fibers and compare them directly with nylon, Kevlar, and aluminum monofilament fibers under the same supersonic impact conditions. The in situ dynamics and kinetic parameters of the fibers show that the kinetic energy absorption characteristics of the carbon nanotube fibers surpass all other fibers. This study provides insight into the strain-rate-dependent strengthening mechanics of an ensemble of nanomaterials for the development of high-performance fibers used in body armor and other protective nanomaterials possessing exceptional stability in various harsh environments.
引用
收藏
页码:3519 / 3526
页数:8
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