A novel and selective method for hydrolysis of acetals and ketals

被引：39
作者：
Lee, ASY
Cheng, CL
机构：
[1] Department of Chemistry, Tamkang University, Tamsui
来源：
TETRAHEDRON | 1997年 / 53卷 / 42期
关键词：
D O I：
10.1016/S0040-4020(97)00993-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of cyclic and acyclic acetals and ketals were hydrolyzed to their corresponding carbonyl compounds by a catalytic amount of CBr4 (20%) in CH3CN/H2O solvent mixture under different energy sources, thermal or ultrasound. The highly chemoselective hydrolysis can be achieved under ultrasonic reaction condition. (C) 1997 Elsevier Science Ltd.
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页码：14255 / 14262
页数：8
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