Poly[[bis(benzimidazole)manganese(II)]-di-μ-1,5-dicyanamido]

被引:4
作者
Wang, Shou-Wu
Ge, Hai-Yan
Yang, Jian-Hu
Li, Bao-Long [1 ]
Zhang, Yong
机构
[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Province, Suzhou 215123, Peoples R China
[2] Huaihai Inst Technol, Donggang Coll, Lianyungang 222069, Peoples R China
关键词
D O I
10.1107/S1600536806021040
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title complex, [Mn(C2N3)(2)(C7H6N2)(2)](n) or [Mn(dca)(2)(bim)(2)](n), where dca is dicyanamide and bim is benzimidazole, each Mn-II atom is located on a center of symmetry and is in a six-coordinated distorted octahedral environment. Four N atoms from four dca ligands fill the equatorial positions, and two N atoms from two bim ligands occupy the axial positions. The dicyanamide ligands adopt an end-to-end coordination mode and link the Mn atoms to form a two-dimensional network.
引用
收藏
页码:M1646 / M1648
页数:3
相关论文
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