3D Nitrogen-rich metal-organic frameworks: opportunities for safer energetics

被引：106
|
作者：
Zhang, Jiaheng [1 ]
Shreeve, Jean'ne M. [1 ]
机构：
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 06期
关键词：
COORDINATION POLYMERS; CRYSTAL-STRUCTURES; ENERGY; SALTS; MOFS; DETONATION; THERMOSTABILITY; PERFORMANCE; STABILITY; STORAGE;
D O I：
10.1039/c5dt04456a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal-organic frameworks, particularly those coordinated with nitrogen-rich ligands, are extremely versatile materials. Here the structural factors and performances of 1D and 2D energetic MOFs are compared briefly with those of 3D species. Advantages of hydrothermal in situ synthesis, properties of azole-based ligands, and choices of environmentally friendly metal ions for 3D energetic MOFs are also explored.
引用
收藏
页码：2363 / 2368
页数：6
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