Structural Tracking of a Bimolecular Reaction in Solution by Time-Resolved X-Ray Scattering

被引：42
作者：
Haldrup, Kristoffer [1 ,2 ]
Christensen, Morten [1 ,2 ]
Cammarata, Marco [3 ]
Kong, Qingyu [3 ]
Wulff, Michael [3 ]
Mariager, Simon O. [1 ,2 ]
Bechgaard, Klaus [1 ,2 ]
Feidenhans'l, Robert [1 ,2 ]
Harrit, Niels [1 ,2 ]
Nielsen, Martin M. [1 ,2 ]
机构：
[1] Univ Copenhagen, Ctr Mol Movies, Dept Chem, DK-2100 Copenhagen, Denmark
[2] Univ Copenhagen, Niels Bohr Inst, DK-2100 Copenhagen, Denmark
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 23期
关键词：
exciplexes; photochemistry; platinum; X-ray scattering; EXCITED-STATE; DIFFRACTION; PROBE; PUMP;
D O I：
10.1002/anie.200900741
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Molecular movies: Time-resolved X-ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis-μ-diphosphito-1 κ P:2κ P F′-diplatinate](4-) (PtPOP*) and thallium ions. In the exciplex one thallium(I) and two platinum(II) ions are found to be collinear. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4180 / 4184
页数：5
相关论文
共 50 条
  • [31] Laser plasma x-ray source for ultrafast time-resolved x-ray absorption spectroscopy
    Miaja-Avila, L.
    O'Neil, G. C.
    Uhlig, J.
    Cromer, C. L.
    Dowell, M. L.
    Jimenez, R.
    Hoover, A. S.
    Silverman, K. L.
    Ullom, J. N.
    STRUCTURAL DYNAMICS-US, 2015, 2 (02):
  • [32] An X-ray image intensifier for microsecond time-resolved experiments
    Yagi, N.
    Aoyama, K.
    JOURNAL OF INSTRUMENTATION, 2015, 10
  • [33] Time-Resolved X-ray Absorption Spectroscopy in (Photo)Electrochemistry
    Fracchia, Martina
    Ghigna, Paolo
    Vertova, Alberto
    Rondinini, Sandra
    Minguzzi, Alessandro
    SURFACES, 2018, 1 (01): : 138 - 150
  • [34] Time-Resolved Single-Crystal X-Ray Crystallography
    Raithby, Paul R.
    21ST CENTURY CHALLENGES IN CHEMICAL CRYSTALLOGRAPHY I: HISTORY AND TECHNICAL DEVELOPMENTS, 2020, 185 : 239 - 271
  • [35] Watching proteins function with time-resolved x-ray crystallography
    Srajer, Vukica
    Schmidt, Marius
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2017, 50 (37)
  • [36] Time-Resolved X-Ray Diffraction: The Dynamics of the Chemical Bond
    Moller, Klaus B.
    Henriksen, Niels E.
    MOLECULAR ELECTRONIC STRUCTURES OF TRANSITION METAL COMPLEXES I, 2012, 142 : 185 - 211
  • [37] Kinetics of lysozyme refolding: Structural characterization of a non-specifically collapsed state using time-resolved X-ray scattering
    Chen, LL
    Wildegger, G
    Kiefhaber, T
    Hodgson, KO
    Doniach, S
    JOURNAL OF MOLECULAR BIOLOGY, 1998, 276 (01) : 225 - 237
  • [38] 100 ps time-resolved solution scattering utilizing a wide-bandwidth X-ray beam from multilayer optics
    Ichiyanagi, K.
    Sato, T.
    Nozawa, S.
    Kim, K. H.
    Lee, J. H.
    Choi, J.
    Tomita, A.
    Ichikawa, H.
    Adachi, S.
    Ihee, H.
    Koshihara, S.
    JOURNAL OF SYNCHROTRON RADIATION, 2009, 16 : 391 - 394
  • [39] Time-resolved structural studies at synchrotrons and X-ray free electron lasers: opportunities and challenges
    Neutze, Richard
    Moffat, Keith
    CURRENT OPINION IN STRUCTURAL BIOLOGY, 2012, 22 (05) : 651 - 659
  • [40] Demonstration of a time-resolved x-ray scattering instrument utilizing the full-repetition rate of x-ray pulses at the Pohang Light Source
    Jo, Wonhyuk
    Eom, Intae
    Landahl, Eric C.
    Lee, Sooheyong
    Yu, Chung-Jong
    REVIEW OF SCIENTIFIC INSTRUMENTS, 2016, 87 (03)
12345