Structural Tracking of a Bimolecular Reaction in Solution by Time-Resolved X-Ray Scattering

被引：42
作者：
Haldrup, Kristoffer [1 ,2 ]
Christensen, Morten [1 ,2 ]
Cammarata, Marco [3 ]
Kong, Qingyu [3 ]
Wulff, Michael [3 ]
Mariager, Simon O. [1 ,2 ]
Bechgaard, Klaus [1 ,2 ]
Feidenhans'l, Robert [1 ,2 ]
Harrit, Niels [1 ,2 ]
Nielsen, Martin M. [1 ,2 ]
机构：
[1] Univ Copenhagen, Ctr Mol Movies, Dept Chem, DK-2100 Copenhagen, Denmark
[2] Univ Copenhagen, Niels Bohr Inst, DK-2100 Copenhagen, Denmark
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 23期
关键词：
exciplexes; photochemistry; platinum; X-ray scattering; EXCITED-STATE; DIFFRACTION; PROBE; PUMP;
D O I：
10.1002/anie.200900741
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Molecular movies: Time-resolved X-ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis-μ-diphosphito-1 κ P:2κ P F′-diplatinate](4-) (PtPOP*) and thallium ions. In the exciplex one thallium(I) and two platinum(II) ions are found to be collinear. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4180 / 4184
页数：5
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