Structural Tracking of a Bimolecular Reaction in Solution by Time-Resolved X-Ray Scattering

被引：43

作者：

Haldrup, Kristoffer ^{[1
,2
]}

Christensen, Morten ^{[1
,2
]}

Cammarata, Marco ^{[3
]}

Kong, Qingyu ^{[3
]}

Wulff, Michael ^{[3
]}

Mariager, Simon O. ^{[1
,2
]}

Bechgaard, Klaus ^{[1
,2
]}

Feidenhans'l, Robert ^{[1
,2
]}

Harrit, Niels ^{[1
,2
]}

Nielsen, Martin M. ^{[1
,2
]}

机构：

[1] Univ Copenhagen, Ctr Mol Movies, Dept Chem, DK-2100 Copenhagen, Denmark

[2] Univ Copenhagen, Niels Bohr Inst, DK-2100 Copenhagen, Denmark

[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 23期

关键词：

exciplexes; photochemistry; platinum; X-ray scattering; EXCITED-STATE; DIFFRACTION; PROBE; PUMP;

D O I：

10.1002/anie.200900741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular movies: Time-resolved X-ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis-μ-diphosphito-1 κ P:2κ P F′-diplatinate](4-) (PtPOP*) and thallium ions. In the exciplex one thallium(I) and two platinum(II) ions are found to be collinear. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：4180 / 4184

页数：5

相关论文

共 28 条

[1]

ALSNIELSEN J, 2000, ELEMENTS MODERN XRAY, P112

[2] Time-resolved x-ray diffraction: Statistical theory and its application to the photo-physics of molecular iodine [J].

Bratos, S ;

Mirloup, F ;

Vuilleumier, R ;

Wulff, M .

JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (24) :10615-10625

[3] Impulsive solvent heating probed by picosecond x-ray diffraction [J].

Cammarata, M ;

Lorenc, M ;

Kim, TK ;

Lee, JH ;

Kong, QY ;

Pontecorvo, E ;

Lo Russo, M ;

Schiró, G ;

Cupane, A ;

Wulff, M ;

Ihee, H .

JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (12)

[4] SPECTROSCOPIC PROPERTIES AND REDOX CHEMISTRY OF THE PHOSPHORESCENT EXCITED-STATE OF PT2(P2O5)4H84- [J].

CHE, CM ;

BUTLER, LG ;

GRAY, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (26) :7796-7797

[5] Capturing a photoexcited molecular structure through time-domain X-ray absorption fine structure [J].

Chen, LX ;

Jäger, WJH ;

Jennings, G ;

Gosztola, DJ ;

Munkholm, A ;

Hessler, JP .

SCIENCE, 2001, 292 (5515) :262-264

[6] Time-Resolved X-ray Scattering of an Electronically Excited State in Solution. Structure of the 3A2u State of Tetrakis-μ-pyrophosphitodiplatinate(II) [J].

Christensen, Morten ;

Haldrup, Kristoffer ;

Bechgaard, Klaus ;

Feidenhans'l, Robert ;

Kong, Qingyu ;

Cammarata, Marco ;

Lo Russo, Manuela ;

Wulff, Michael ;

Harrit, Niels ;

Nielsen, Martin Meedom .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :502-508

[7] LUMINESCENT METAL-METAL-BONDED EXCIPLEXES INVOLVING TETRAKIS 9(MU-DIPHOSPHITO)DIPLATINATE(II) AND THALLIUM(I) [J].

CLODFELTER, SA ;

DOEDE, TM ;

BRENNAN, BA ;

NAGLE, JK ;

BENDER, DP ;

TURNER, WA ;

LAPUNZINA, PM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (25) :11379-11386

[8]

Flannery B., 1986, Numerical Recipes

[9] Picosecond calorimetry:: Time-resolved x-ray diffraction studies of liquid CH2Cl2 [J].

Georgiou, Panayiotis ;

Vincent, Jonathan ;

Andersson, Magnus ;

Wohri, Annemarie B. ;

Gourdon, Pontus ;

Poulsen, Jens ;

Davidsson, Jan ;

Neutze, Richard .

JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (23)

[10] On the theory of time-resolved X-ray diffraction [J].

Henriksen, Niels E. ;

Moller, Klaus B. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (02) :558-567