Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal-organic framework

被引：40
作者：
Bezrukov, Andrey A. [1 ]
Tornroos, Karl W. [1 ]
Le Roux, Erwan [1 ]
Dietzel, Pascal D. C. [1 ]
机构：
[1] Univ Bergen, Dept Chem, POB 7803, N-5020 Bergen, Norway
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 22期
关键词：
SECONDARY BUILDING UNITS; COORDINATION POLYMER; CRYSTAL-STRUCTURE; ZR-MOFS; LINKER; STABILITY; PHOSPHINE; COATINGS; LIGAND; COPOLYMERS;
D O I：
10.1039/c8cc00507a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two zirconium-organic frameworks were synthesized by exchanging the acetate ligands in [Zr12O8(OH)(8)(CH3COO)(24)] with polydentate linkers. Partial substitution of acetate groups by a phosphine based linker yielded a new porous framework with this unique dimeric Zr-12 cluster unit as molecular building block. More exhaustive substitution of acetate resulted in cleavage of the Zr-12 unit and formation of UiO-67.
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收藏
页码：2735 / 2738
页数：4
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