Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal-organic framework

被引：43

作者：

Bezrukov, Andrey A. ^{[1
]}

Tornroos, Karl W. ^{[1
]}

Le Roux, Erwan ^{[1
]}

Dietzel, Pascal D. C. ^{[1
]}

机构：

[1] Univ Bergen, Dept Chem, POB 7803, N-5020 Bergen, Norway

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 22期

关键词：

SECONDARY BUILDING UNITS; COORDINATION POLYMER; CRYSTAL-STRUCTURE; ZR-MOFS; LINKER; STABILITY; PHOSPHINE; COATINGS; LIGAND; COPOLYMERS;

D O I：

10.1039/c8cc00507a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two zirconium-organic frameworks were synthesized by exchanging the acetate ligands in [Zr12O8(OH)(8)(CH3COO)(24)] with polydentate linkers. Partial substitution of acetate groups by a phosphine based linker yielded a new porous framework with this unique dimeric Zr-12 cluster unit as molecular building block. More exhaustive substitution of acetate resulted in cleavage of the Zr-12 unit and formation of UiO-67.

引用

页码：2735 / 2738

页数：4

共 59 条

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