Facilely prepared oxidized carbon Fiber@Co3O4@RGO as negative electrode for a novel asymmetric supercapacitor with high areal energy and power density

被引:28
作者
Wang, Weigang [1 ]
Liu, Yajun [1 ]
Wang, Mingqian [1 ]
Ren, Guohong [1 ]
Wu, Shishan [1 ]
Shen, Jian [1 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, 163 Xianlin Ave, Nanjing 210023, Jiangsu, Peoples R China
关键词
Co3O4; RGO; Mutil-layer structure; Asymmetric supercapacitors; HIGH-PERFORMANCE; ELECTROCHEMICAL PERFORMANCE; CAPACITANCE; COMPOSITE; CO3O4; OXIDE; NANOPARTICLES; BEHAVIOR;
D O I
10.1016/j.apsusc.2018.04.092
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Supercapacitors, a promising kind of energy storage and transfer device for filling the gaps between traditional capacitors and lithium-ion batteries, are widely studied and used recently. A novel asymmetric supercapacitor was fabricated assembling Co3O4@RGO layer covered oxidized carbon fiber (OCF) and a mutil-layer OCF@Au@MnO2@PIn electrode. The multi-layer structure of these electrodes and the synergistic effects among each component were confirmed and guaranteed outstanding electrochemical performances. This novel supercapacitor shows excellent electrochemical performances with a high areal energy density of 1.83 mWh cm(-2) at an areal power density of 3.2 mW cm(-2) and long cycling life of 91.75% capacitance retention after 5000 cycles. Thus, this kind of portable supercapacitor with high performances not only might be used commercially but also provides a strategy for designing highperformance electrodes for supercapacitors. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:66 / 76
页数:11
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