Tris{bis[hydrotris(1-pyrazolyl)borato-κ3N2,N2′,N2"]iron(III)} hexaisothiocyanatoiron (III)

被引：1
作者：
Wang, S [1 ]
Li, YZ [1 ]
Zuo, JL [1 ]
Li, CH [1 ]
You, XZ [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷 / 06期
关键词：
D O I：
10.1107/S0108270104008741
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Fe(C9H10BN6)(2)](3)[Fe(NCS)(6)] or [FeIII-(Tp)(2)](3)[Fe-III(NCS)(6)] [ Tp is hydrotris(1-pyrazolyl) borate], crystallizes in space group R(3) over bar; the asymmetric unit comprises one-half of an [Fe(Tp)(2)](+) cation, with its Fe atom on a crystallographic inversion centre, and one-sixth of an [Fe(NCS)(6)](3-) anion, on a site of 3 symmetry. The anions and cations are stacked into a three-dimensional supramolecular aggregate via two distinct types of weak C-H...pi interactions.
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页码：M258 / M260
页数：3
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