Synthesis and structures of cyclopentadienyl N-heterocyclic carbene copper(I) complexes

被引：20

作者：

Ren, Hongping ^{[1
]}

Zhao, Xi ^{[1
]}

Xu, Shansheng ^{[1
]}

Song, Haibin ^{[1
]}

Wang, Baiquan ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 19期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

cyclopentadienyl; copper; N-heterocyclic carbene; crystal structure; CATALYZED CONJUGATE ADDITION; STABLE CARBENES; REACTIVITY; LIGANDS; CHEMISTRY; SILVER(I); CARBONYL; METAL; NHC; PENTAMETHYLCYCLOPENTADIENYLCOPPER;

D O I：

10.1016/j.jorganchem.2006.06.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of cyclopentadienyl N-heterocyclic carbene copper complexes CpCu(NHC) were synthesized and structurally characterized. The effect of the substituents at the nitrogen atom of the NHC ligands on the structures and thermally stability was discussed. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：4109 / 4113

页数：5

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