Polyionic polymers - heterogeneous media for metal nanoparticles as catalyst in Suzuki-Miyaura and Heck-Mizoroki reactions under flow conditions

被引：62
|
作者：
Mennecke, Klaas
Kirschning, Andreas [1 ]
机构：
[1] Leibniz Univ Hannover, Inst Organ Chem, D-30167 Hannover, Germany
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 5卷
关键词：
Heck-Mizoroki reaction; heterogeneous catalysis; ion exchange resin; microreactor; monolith; palladium; Suzuki-Miyaura reaction; CROSS-COUPLING REACTIONS; PALLADIUM CATALYSTS; ORGANIC-SYNTHESIS; BATCH; COMPOSITES; REACTORS; SYSTEM; NANOCLUSTERS; PRECATALYSTS; CLUSTERS;
D O I：
10.3762/bjoc.5.21
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The preparation of monolithic polyionic supports which serve as efficient heterogeneous supports for palladium(0) nanoparticles is described. These functionalized polymers were incorporated inside a flow reactor and employed in Suzuki-Miyaura and Heck cross couplings under continuous flow conditions.
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页数：6
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