Correlation strength and orbital differentiation across the phase diagram of plutonium metal

We compare the trends on the strength of electronic correlations across the different phases of elemental Pu focusing on its site and orbital dependence, using a combination of density functional theory (DFT) and dynamical mean-field theory (DMFT) calculations within the vertex corrected one crossing approximation. We find that Pu-5f states are more correlated in S-Pu, followed by some crystallographic sites in alpha and beta phases. In addition, we observe that Pu-5f(5/2) and Pu-5f(7/2) orbital differentiation is a general feature of this material, as is site differentiation in the low-symmetry phases. The Pu-5f(5/2) states show Fermi liquid like behavior, whereas the Pu-5f(7/)(2) states remaining incoherent down to very low temperatures. We correlate the correlation strength in the different phases to their structure and the Pu-5f occupancy of their crystallographic sites.