Realizing both High Energy and High Power Densities by Twisting Three Carbon-Nanotube-Based Hybrid Fibers

被引:105
作者
Zhang, Ye [1 ,2 ]
Zhao, Yang [1 ,2 ]
Cheng, Xunliang [1 ,2 ]
Weng, Wei [1 ,2 ]
Ren, Jing [1 ,2 ]
Fang, Xin [1 ,2 ]
Jiang, Yishu [1 ,2 ]
Chen, Peining [1 ,2 ]
Zhang, Zhitao [1 ,2 ]
Wang, Yonggang [3 ,4 ]
Peng, Huisheng [1 ,2 ]
机构
[1] Fudan Univ, Dept Macromol Sci, Collaborat Innovat Ctr Polymers & Polymer Composi, State Key Lab Mol Engn Polymers, Shanghai 200438, Peoples R China
[2] Fudan Univ, Adv Mat Lab, Shanghai 200438, Peoples R China
[3] Fudan Univ, iChEM Collaborat Innovat Ctr Chem Energy Mat, Inst New Energy, Dept Chem, Shanghai 200438, Peoples R China
[4] Fudan Univ, iChEM Collaborat Innovat Ctr Chem Energy Mat, Inst New Energy, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200438, Peoples R China
关键词
carbon nanotubes; energy storage; fibers; hybrid device; wearable electronics; LITHIUM-ION BATTERY; ALL-SOLID-STATE; SPINEL LIMN2O4; SUPERCAPACITORS; ACTUATION; STORAGE;
D O I
10.1002/anie.201506142
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Energy storage devices, such as lithium-ion batteries and supercapacitors, are required for the modern electronics. However, the intrinsic characteristics of low power densities in batteries and low energy densities in supercapacitors have limited their applications. How to simultaneously realize high energy and power densities in one device remains a challenge. Herein a fiber-shaped hybrid energy-storage device (FESD) formed by twisting three carbon nanotube hybrid fibers demonstrates both high energy and power densities. For the FESD, the energy density (50 mWhcm(-3) or 90 Whkg(-1)) many times higher than for other forms of supercapacitors and approximately 3 times that of thin-film batteries; the power density (1 Wcm(-3) or 5970 Wkg(-1)) is approximately 140 times of thin-film lithium-ion battery. The FESD is flexible, weave-able and wearable, which offers promising advantages in the modern electronics.
引用
收藏
页码:11177 / 11182
页数:6
相关论文
共 33 条
[1]   Mitigation of the irreversible capacity and electrolyte decomposition in a LiNi0.5Mn1.5O4/nano-TiO2 Li-ion battery [J].
Brutti, Sergio ;
Gentili, Valentina ;
Reale, Priscilla ;
Carbone, Lorenzo ;
Panero, Stefania .
JOURNAL OF POWER SOURCES, 2011, 196 (22) :9792-9799
[2]   High-Performance Energy-Storage Architectures from Carbon Nanotubes and Nanocrystal Building Blocks [J].
Chen, Zheng ;
Zhang, Dieqing ;
Wang, Xiaolei ;
Jia, Xilai ;
Wei, Fei ;
Li, Hexing ;
Lu, Yunfeng .
ADVANCED MATERIALS, 2012, 24 (15) :2030-2036
[3]   High-Performance Supercapacitors Based on Intertwined CNT/V2O5 Nanowire Nanocomposites [J].
Chen, Zheng ;
Augustyn, Veronica ;
Wen, Jing ;
Zhang, Yuewei ;
Shen, Meiqing ;
Dunn, Bruce ;
Lu, Yunfeng .
ADVANCED MATERIALS, 2011, 23 (06) :791-+
[4]   Carbon-coated Li4Ti5O12 as a high rate electrode material for Li-ion intercalation [J].
Cheng, Liang ;
Li, Xi-Li ;
Liu, Hai-Jing ;
Xiong, Huan-Ming ;
Zhang, Ping-Wei ;
Xia, Yong-Yao .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (07) :A692-A697
[5]   Flexible and Wire-Shaped Micro-Supercapacitor Based on Ni(OH)2-Nanowire and Ordered Mesoporous Carbon Electrodes [J].
Dong, Xiaoli ;
Guo, Ziyang ;
Song, Yanfang ;
Hou, Mengyan ;
Wang, Jianqiang ;
Wang, Yonggang ;
Xia, Yongyao .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (22) :3405-3412
[6]   A Novel Electromechanical Actuation Mechanism of a Carbon Nanotube Fiber [J].
Guo, Wenhan ;
Liu, Chao ;
Zhao, Fangyuan ;
Sun, Xuemei ;
Yang, Zhibin ;
Chen, Tao ;
Chen, Xuli ;
Qiu, Longbin ;
Hu, Xinhua ;
Peng, Huisheng .
ADVANCED MATERIALS, 2012, 24 (39) :5379-5384
[7]   Flexible electronic futures [J].
Hamers, RJ .
NATURE, 2001, 412 (6846) :489-490
[8]   Asymmetric supercapacitors based on β-Ni(OH)2 nanosheets and activated carbon with high energy density [J].
Huang, Jichun ;
Xu, Panpan ;
Cao, Dianxue ;
Zhou, Xiaobin ;
Yang, Sainan ;
Li, Yiju ;
Wang, Guiling .
JOURNAL OF POWER SOURCES, 2014, 246 :371-376
[9]   Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics [J].
Kou, Liang ;
Huang, Tieqi ;
Zheng, Bingna ;
Han, Yi ;
Zhao, Xiaoli ;
Gopalsamy, Karthikeyan ;
Sun, Haiyan ;
Gao, Chao .
NATURE COMMUNICATIONS, 2014, 5
[10]   Cable-Type Flexible Lithium Ion Battery Based on Hollow Multi-Helix Electrodes [J].
Kwon, Yo Han ;
Woo, Sang-Wook ;
Jung, Hye-Ran ;
Yu, Hyung Kyun ;
Kim, Kitae ;
Oh, Byung Hun ;
Ahn, Soonho ;
Lee, Sang-Young ;
Song, Seung-Wan ;
Cho, Jaephil ;
Shin, Heon-Cheol ;
Kim, Je Young .
ADVANCED MATERIALS, 2012, 24 (38) :5192-5197