Novel 1,3,2-diazaphospholidines with pseudodipeptide substituents

被引：1

作者：

Chuchelkin, I. V. ^{[1
]}

Gavrilov, V. K. ^{[1
]}

Firsin, I. D. ^{[1
]}

Zimarev, V. S. ^{[1
]}

Novikov, I. M. ^{[1
]}

Maksimova, M. G. ^{[1
]}

Shiryaev, A. A. ^{[1
]}

Zheglov, S. V. ^{[1
]}

Tafeenko, V. A. ^{[2
]}

Chernyshev, V. V. ^{[2
]}

Gavrilov, K. N. ^{[1
]}

机构：

[1] Ryazan State Univ, Chem Dept, 46 Svoboda St, Ryazan 390000, Russia

[2] Lomonosov Moscow State Univ, Dept Chem, GSP 1, Moscow 119991, Russia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2019年 / 194卷 / 4-6期

基金：

俄罗斯科学基金会;

关键词：

Chiral; 1; 3; 2-diazaphospholidine; pseudodipeptide; Pd-catalyzed asymmetric allylation; Rh-catalyzed asymmetric hydrogenation; ENANTIOSELECTIVE ALLYLATION; CONTAINING LIGANDS; PALLADIUM; EFFICIENT; DERIVATIVES;

D O I：

10.1080/10426507.2018.1540484

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral 1,3,2-diazaphospholidine with pseudodipeptide substituents was prepared. This asymmetric inducer provided up to 84% ee in the Pd-catalyzed asymmetric allylic alkylation of (E)-1,3-diphenylallyl acetate with dimethyl malonate, and up to 53% ee in the Rh-catalyzed asymmetric hydrogenation of (Z)-methyl 2-acetamido-3-phenylacrylate. [GRAPHICS] .

引用

页码：493 / 496

页数：4

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