Pyrolysis of microalgae residues - A kinetic study

被引:107
作者
Bui, Hau-Huu [1 ]
Khanh-Quang Tran [2 ]
Chen, Wei-Hsin [3 ]
机构
[1] Chulalongkorn Univ, Petr & Petrochem Coll, Bangkok 10330, Thailand
[2] Norwegian Univ Sci & Technol, Dept Energy & Proc Engn, NO-7491 Trondheim, Norway
[3] Natl Cheng Kung Univ, Dept Aeronaut & Astronaut, Tainan 701, Taiwan
关键词
Microalgae residue; Non-isothermal pyrolysis; Kinetic modelling; Five pseudo-components model; LOW-LIPID MICROALGAE; THERMOGRAVIMETRIC ANALYSIS; CHLORELLA; BIOMASS; DEVOLATILIZATION; TORREFACTION; BIOFUELS; ENERGY; MODEL; WOOD;
D O I
10.1016/j.biortech.2015.08.069
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Pyrolysis of residues from the oil extraction process of two types of microalgae, Chlamydomonas (C. sp. JSC4) and Chlorella sorokiniana (C. Sorokiniana CY1) was studied by means of a thermogravimetric analyzer. Five pseudo-components (hemicellulose, cellulose, lignin, lipid and protein) model with n = 1 or n # 1 was assumed for a kinetic analysis of the collected pyrolysis data. The model with n # 1 resulted in a slightly better fit quality and reasonable kinetic parameters. The calculated activation energy of hemicellulose, cellulose, lignin, lipid, protein was 115.12-117.12 kJ/mol, 181.67-198.30 kJ/mol, 61.74-62.75 kJ/mol, 104.93-114.14 kJ/mol and 90.75-99.31 kJ/mol, respectively, for C. sp. JSC4; and 113.12-117.12 kJ/mol, 218.73-28.79 kJ/mol, 64.77-66.39 kJ/mol, 131.97-143.63 kJ/mol and 108.03-118.13 kJ/mol, respectively, for C. Sorokiniana CY1. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:362 / 366
页数:5
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