Strongly Coupled NiCo 2 O 4-rGO Hybrid Nanosheets as a Methanol- Tolerant Electrocatalyst for the Oxygen Reduction Reaction

被引:284
作者
Zhang, Genqiang [1 ,2 ]
Xia, Bao Yu [2 ]
Wang, Xin [2 ]
Lou, Xiong Wen [1 ,2 ]
机构
[1] TUM CREATE, Singapore 138602, Singapore
[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore
基金
新加坡国家研究基金会;
关键词
TEMPERATURE FUEL-CELLS; BIFUNCTIONAL ELECTROCATALYST; COBALT OXIDE; GRAPHENE; NANOPARTICLES; NANOCRYSTALS; CATALYST; PERFORMANCE; NANOTUBES; BATTERIES;
D O I
10.1002/adma.201304683
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Strongly coupled NiCo2O4-rGO hybrid nanosheets are syntheiszed through a cost-effective two-step strategy involving a facile polyol process and subsequent thermal annealing treatment in air. The hybrid nanosheets exhibit impressive electrocatalytic performance for the oxygen reduction reaction (ORR) with a current density and onset potential comparable to those of commercial Pt/C catalyts, while having perfect tolerance to methanol. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2408 / 2412
页数:5
相关论文
共 32 条
[1]   Review of gas diffusion cathodes for alkaline fuel cells [J].
Bidault, F. ;
Brett, D. J. L. ;
Middleton, P. H. ;
Brandon, N. P. .
JOURNAL OF POWER SOURCES, 2009, 187 (01) :39-48
[2]   Nanostructured Pt-alloy electrocatalysts for PEM fuel cell oxygen reduction reaction [J].
Bing, Yonghong ;
Liu, Hansan ;
Zhang, Lei ;
Ghosh, Dave ;
Zhang, Jiujun .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (06) :2184-2202
[3]   MnxCu1-xCo2O4 used as bifunctional electrocatalyst in alkaline medium [J].
De Koninck, Mathieu ;
Marsan, Benoit .
ELECTROCHIMICA ACTA, 2008, 53 (23) :7012-7021
[4]   CuxCo3-xO4 used as bifunctional electrocatalyst -: Physicochemical properties and electrochemical characterization for the oxygen evolution reaction [J].
De Koninck, Mathieu ;
Poirier, Simon-Claude ;
Marsan, Benoit .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (11) :A2103-A2110
[5]   Electrocatalyst approaches and challenges for automotive fuel cells [J].
Debe, Mark K. .
NATURE, 2012, 486 (7401) :43-51
[6]   A Methanol-Tolerant Pt/CoSe2 Nanobelt Cathode Catalyst for Direct Methanol Fuel Cells [J].
Gao, Min-Rui ;
Gao, Qiang ;
Jiang, Jun ;
Cui, Chun-Hua ;
Yao, Wei-Tang ;
Yu, Shu-Hong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (21) :4905-4908
[7]   Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction [J].
Gong, Kuanping ;
Du, Feng ;
Xia, Zhenhai ;
Durstock, Michael ;
Dai, Liming .
SCIENCE, 2009, 323 (5915) :760-764
[8]   Co/CoO Nanoparticles Assembled on Graphene for Electrochemical Reduction of Oxygen [J].
Guo, Shaojun ;
Zhang, Sen ;
Wu, Liheng ;
Sun, Shouheng .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (47) :11770-11773
[9]  
Hamdani M, 2010, INT J ELECTROCHEM SC, V5, P556
[10]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339