Effect of crystallization on the reliability of unipolar resistive-switching in HfO2-based dielectrics

被引:5
作者
Saleh, M. N. [1 ]
Venkatachalam, D. K. [1 ]
Elliman, R. G. [1 ]
机构
[1] Australian Natl Univ, Res Sch Phys & Engn, Dept Elect Mat Engn, Canberra, ACT 0200, Australia
基金
澳大利亚研究理事会;
关键词
ReRAM; Resistive switching; Hafnium oxide; Hafnium silicate; Grain boundary; Amorphous; Unipolar switching; PHASE-SEPARATION; SILICATE FILMS; MEMORY; RRAM;
D O I
10.1016/j.cap.2013.11.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The electroforming and unipolar resistive switching characteristics of as-deposited and annealed HfO2 and Hf0.6Si0.4O2 films are reported. The reliability of HfO2 devices is shown to be significantly degraded by annealing at 600 degrees C, during which the film is observed to crystallize. In contrast, the characteristics of Hf0.6Si0.4O2 devices subjected to the same annealing conditions are found to be unchanged, consistent with the fact that the films remain amorphous. These differences are attributed to the presence of grain boundaries and can have important implications for the use of HfO2 in ReRAM applications. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:S88 / S92
页数:5
相关论文
共 14 条
[1]   Adaptive oxide electronics: A review [J].
Ha, Sieu D. ;
Ramanathan, Shriram .
JOURNAL OF APPLIED PHYSICS, 2011, 110 (07)
[2]   Physical models of size-dependent nanofilament formation and rupture in NiO resistive switching memories [J].
Ielmini, D. ;
Nardi, F. ;
Cagli, C. .
NANOTECHNOLOGY, 2011, 22 (25)
[3]   Effect of HfO2 Crystallinity on Device Characteristics and Reliability for Resistance Random Access Memory [J].
Kim, Ja-Yong ;
Yoo, Jong-Hee ;
Youn, Tae-One ;
Kim, Sook-Joo ;
Kim, Jung-Nam ;
Lee, Sung-Hoon ;
Joo, Moon-Sig ;
Roh, Jae-Sung ;
Park, Sung-Ki .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2011, 14 (08) :H337-H339
[4]   Physical electro-thermal model of resistive switching in bi-layered resistance-change memory [J].
Kim, Sungho ;
Kim, Sae-Jin ;
Kim, Kyung Min ;
Lee, Seung Ryul ;
Chang, Man ;
Cho, Eunju ;
Kim, Young-Bae ;
Kim, Chang Jung ;
Chung, U. -In ;
Yoo, In-Kyeong .
SCIENTIFIC REPORTS, 2013, 3
[5]   Resistive Switching by Voltage-Driven Ion Migration in Bipolar RRAM-Part II: Modeling [J].
Larentis, Stefano ;
Nardi, Federico ;
Balatti, Simone ;
Gilmer, David C. ;
Ielmini, Daniele .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2012, 59 (09) :2468-2475
[6]   Grain boundary mediated leakage current in polycrystalline HfO2 films [J].
McKenna, K. ;
Shluger, A. ;
Iglesias, V. ;
Porti, M. ;
Nafria, M. ;
Lanza, M. ;
Bersuker, G. .
MICROELECTRONIC ENGINEERING, 2011, 88 (07) :1272-1275
[7]   Influence of phase separation on electrical properties of ALD Hf-silicate films with various Si concentrations [J].
Park, Tae Joo ;
Kim, Jeong Hwan ;
Jang, Jae Hyuck ;
Na, Kwang Duk ;
Hwang, Cheol Seong ;
Yoo, Jeong Ho .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (05) :H121-H123
[9]   Local resistance switching at grain and grain boundary surfaces of polycrystalline tungsten oxide films [J].
Shang, Da-Shan ;
Shi, Lei ;
Sun, Ji-Rong ;
Shen, Bao-Gen .
NANOTECHNOLOGY, 2011, 22 (25)
[10]   Grazing-incidence small angle x-ray scattering studies of phase separation in hafnium silicate films [J].
Stemmer, S ;
Li, YL ;
Foran, B ;
Lysaght, PS ;
Streiffer, SK ;
Fuoss, P ;
Seifert, S .
APPLIED PHYSICS LETTERS, 2003, 83 (15) :3141-3143